45. Synthesis of (-)-Octalactin A by a Strategic Vanadium-Catalyzed
Oxidative Kinetic Resolution
Radosevich, A. T.; Chan, V. S.; Shih, H.; Toste, F. D. Angew. Chem. Int. Ed. 2008,, ASAP

44. Gold-Catalyzed Cycloisomerization of 1,5-Allenynes via Dual
Activation of an Ene Reaction
Cheong, P. H.; Morganelli, P.; Luzung, M. R.; Houk, K. N.; Toste, F. D. J. Am. Chem. Soc. 2008, 130, 4517-4526

43. Fluorenes and Styrenes by Au(I)-Catalyzed Annulation of
Enynes and Alkynes
Gorin, D. J.; Watson, I. D. G.; Toste, F. D. J. Am. Chem. Soc. 2008, 130, 3736-3737

42. Cobalt Dinitrosoalkane Complexes in the C-H Functionalization
of Olefins
Schomaker, J. M.; Boyd, W. C.; Stewart, I. C.; Toste, F. D.; Bergman, R. G. J. Am. Chem. Soc. 2008, 130, 3777-3779

41. Synthesis and Structural Characterization of Isolable Phosphine
Coinage Metal π-Complexes
Shapiro, N. D.; Toste, F. D. Proc. Nat. Acad. Sci. U.S.A. 2008, 105, 2779-2782

40. Analysis of an Unprecedented Mechanism for the Catalytic
Hydrosilylation of Carbonyl Compounds
Nolin, K. A.; Krumper, J. R.; Pluth M. D.; Bergman, R. D.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 14684-14696

39. Pd-Catalyzed Dynamic Kinetic Enantioselective Arylation of
Silylphosphines
Chan, V. S.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 15122-15123

38. Au(I)-Catalyzed Enantioselective 1,3-Dipolar Cycloadditions of
Munchnones with Electron-Deficient Alkenes
Melhado, A. D.; Luparia, M.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 12638-12639

37. Gold(I)-Catalyzed [2 + 2]-Cycloaddition of Allenenes
Luzung, M. R.; Mauleon, P.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 12402-12403

36. A Powerful Chiral Counterion Strategy for Asymmetric Transition
Metal Catalysis
Hamilton, G. L.; Kang, E. J.; Mba, M.; Toste, F. D. Science 2007, 317, 496-499

35. Gold(I)-Catalyzed Oxidative Rearrangements
Witham, C. A.; Mauleon, P.; Shapiro, N. D.; Sherry, B. D.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 5838-5839

34. Total Synthesis of (+)-Fawcettimine
Linghu, X.; Kennedy-Smith, J. J.; Toste, F. D. Angew. Chem. Int. Ed. 2007, 46, 7671-7673

33. Review: Relativistic Effects in Homogeneous Gold Catalysis
Gorin, D.J.; Toste, F. D. Nature 2007, 446, 395.

32. Rearrangement of Alkynyl Sulfoxides Catalyzed by Gold(I)
Complexes
Shapiro, N. D.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 4160-4161.

31. Palladium-Catalyzed Enantioselective Cyclization of
Silyloxy-1,6-Enynes
Corkey, B. K.; Toste, F. D. J. Am. Chem. Soc. 2007, 129,2764-2765.

30. Gold(I)-Catalyzed Enantioselective Intramolecular Hydroamination
of Allenes
LaLonde, R. L.; Sherry, B. D.; Kang, E. J.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 2452-2453.

29. Gold(I)-Catalyzed Synthesis of Functionalized Cyclopentadienes
Lee, J. H.; Toste, F. D. Angew. Chem. Int. Ed. 2007, 46, 912-914.

28. Synthesis of Benzonorcaradienes by Gold(I)-Catalyzed [4+3]
Annulation
Gorin, D. J; Dube, P.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 14480-14481.

27. Enantioselective Synthesis of γ-Hydroxyenones by Chiral Base-
Catalyzed Kornblum DeLaMare Rearrangement
Staben, S. T.; Linghu, X.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 12658-12659.

26. Synthesis of Indenyl Ethers by Gold(I)-Catalyzed Intramolecular
Carboalkoxylation of Alkynes
Dubé, P.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 12062-12063.

25. Stereoselective Synthesis of Vinylsilanes by a Gold(I)-Catalyzed
Acetylenic Sila-Cope Rearrangement
Horino, Y.; Luzung, M. R.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 11364-11365.

24. Gold(I)-Catalyzed Cyclizations of Silyl Enol Ethers: Application
to the Synthesis of (+)-Lycopladine A
Staben, S. T.; Kennedy-Smith, J. J.; Huang, D.; Corkey, B. K.; Lalonde, R. L.; Toste, F. D. Angew. Chem. Int. Ed. 2006, 45, 5991-5994.

23. Gold(I)-Catalyzed Synthesis of Dihydropyrans
Sherry, B. D; Maus, L.; Laforteza, B. N.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 8132-8133.

22. Synthesis of Aromatic Ketones by a Transition Metal-Catalyzed
Tandem Sequence
Zhao, J.; Hughes, C. O.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 7436-7437.

20. Asymmetric Catalytic Synthesis of P-Stereogenic Phosphines via a
Nucleophilic Ruthenium Phosphido Complex
Chan, V. S.; Stewart, I. C.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 2786-2787.

19. Gold(I)-Catalysed Stereoselective Olefin Cyclopropanation
Johansson, M. J.; Gorin, D. J.; Staben, S. T.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 18002-18003.

18. Living Ring-Opening Polymerization of N-Sulfonylaziridines: Synthesis
of High Molecular Weight Linear Polyamines
Stewart, I. C.; Lee, C. C.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 17616-17617.

17. Catalytic Enantioselective Conia-Ene Reaction
Corkey, B. K.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 17168-17169.

16. Enantioselective Reduction of Imines Catalyzed by a
Rhenium(V)-Oxo Complex
Nolin, K. A.; Ahn, R. W.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 12462-12463.

15. Gold(I)-Catalyzed Intramolecular Acetylenic Schmidt Reaction
Gorin, D. J.; Davis, N. R.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 11260-11261.

14. Gold(I)-Catalyzed Ring Expansion of Cyclopropanols and
Cyclobutanols
Markham, J. P.; Staben, S. T.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 9708-9709.

13. A Re(V)-Catalyzed C-N Bond-Forming Route to Human
Lipoxygenase Inhibitors
Ohri, R. V.; Radosevich, A. T.; Hrovat, K. J.; Musich, C.; Huang, D.; Holman, T. R.; Toste, F. D. Org. Lett. 2005, 7, 2501-2504.

12. Synthesis of 2-Cyclopentenones by Gold(I)-Catalyzed
Rautenstrauch Rearrangement
Shi, X.; Gorin, D. J.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 5802-5803.

11. Vanadium-Catalyzed Asymmetric Oxidation of α-Hydroxy Esters
Using Molecular Oxygen as Stoichiometric Oxidant
Radosevich, A. T.; Musich, C.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 1090-1091.

10. Gold(I)-Catalyzed Propargyl Claisen Rearrangement
Sherry, B. D.; Toste, F. D. J. Am. Chem. Soc. 2004, 126, 15978-15979.

9. Gold(I)-Catalyzed 5-endo-dig Carbocyclization of Acetylenic
Dicarbonyl Compounds
Staben, S. T.; Kennedy-Smith, J. J.; Toste, F. D. Angew. Chem. Int. Ed. 2004, 43, 5350-5352.

8. Catalytic Isomerization of 1,5-Enynes to Bicyclo[3.1.0]hexenes
Luzung, M. R.; Markham, J. P.; Toste, F. D. J. Am. Chem. Soc. 2004, 126, 10858-10859.

7. Rhenium-Catalyzed Aromatic Propargylation
Kennedy-Smith, J. J.; Young, L. A.; Toste, F. D. Org. Lett. 2004, 6, 1325-1327.

6. Gold(I)-Catalyzed Conia-Ene Reaction of β-Ketoesters with Alkynes
Kennedy-Smith, J. J.; Staben, S. T.; Toste, F. D. J. Am. Chem. Soc. 2004, 126, 4526-4527.

5. Rhenium(V)-Catalyzed Synthesis of 2-Deoxy-α-glycosides
Sherry, B. D.; Loy, R. N.; Toste, F. D. J. Am. Chem. Soc. 2004, 126, 4510-4511.

4. Rhenium Catalyzed Coupling of Propargyl Alcohols and Allyl Silanes
Luzung, M. R.; Toste, F. D. J. Am. Chem. Soc. 2003, 125, 15760-15761.

3. Phosphine-catalyzed Hydration and Hydroalkoxylation of
Activated Olefins: Use of a Strong Nucleophile to Generate a Strong Base
Stewart, I. C.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2003, 125, 8696-8697.

2. A Mild C-O Bond Formation Catalyzed by a Rhenium-Oxo Complex
Sherry, B. D.; Radosevich, A. T.; Toste, F. D. J. Am. Chem. Soc. 2003, 125, 6076-6077.

1. Reversing the Role of the Metal-oxygen Pi-bond. Chemoselective
Catalytic Reductions with a Rhenium(V)-Dioxo Complex
Kennedy-Smith, J. J.; Nolin, K. A.; Gunterman, H. P.; Toste, F. D. J. Am. Chem. Soc. 2003, 125, 4056-4057.