194. Exploiting non-covalent interactions for catalyst design
Neel, A.J.; Hilton, M.J.; Sigman, M.S.; Toste, F.D. Nature 2017, 543, 637-646

193. Pursuit of Noncovalent Interactions for Strategic Site-Selective Catalysis
Toste, F.D.; Sigman, M.S.; Miller, S.J. Acc. Chem. Res. 2017, 50, 609-615

192. The development and mechanistic investigation of a palladium-catalyzed 1,3-arylfluorination of chromenes
Thornbury, R.T.; Saini, V.; Fernandes, T.A.; Santiago, C.B.; Talbot, E.P.A.; Sigman, M.S.; McKenna, J.M.; Toste, F.D. Chem. Sci. 2017, 8, 2890-2897

191. Redox-based reagents for chemoselective methionine bioconjugation
Lin, S.; Yang, X.; Jia, S.; Weeks, A.M.; Hornsby, M.; Lee, P.S.; Nichiporuk, R.V.; Iavarone, A.T.; Wells, J.A.; Toste, F.D.; Chang, C.J. Science 2017, 355, 597-602

190. ABE Condensation over Monometallic Catalysts:Catalyst Characterization and Kinetics
Goulas, K.A.; Gunbas, G.; Dietrich, P.J.; Sreekumar, S.; Grippo, A.; Chen, J.P.; Gokhale, A.A.; Toste, F.D. ChemCatChem 2017, 9, 677-684

189. New Insights into Aldol Reactions of Methyl Isocyanoacetate Catalyzed by Heterogenized Homogeneous Catalysts
Ye, R.; Zhao, J.; Yuan, B.; Liu, W.; De Araujo, J.R.; Faucher, F.F; Chang, M.; Deraedt, C.V.; Toste, F.D.; Somorjai, G.A. Nano Letters 2017, 17, 584-589

188. High-spatial-resolution mapping of catalytic reactions on single particles
Wu, C.; Wolf, W.J.; Levartovsky, Y.; Bechtel, H.A.; Martin, M.C.; Toste, F.D.; Gross, E. Nature 2017, 541, 511-515

187. Enantioselective Oxidative Homocoupling and Cross-Coupling or 2-Naphthols Catalyzed by Chiral Iron Phosphate Complexes
Narute, S.; Parnes, R.; Toste, F.D.; Pappo, D. J. Am. Chem. Soc. 2016, 138, 16553-16560

186. Development and Analysis of a Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Acrylates Enabled by Chiral Anion Phase Transfer
Yamamoto, E.; Hilton, M.J.; Orlandi, M.; Saini, V.; Toste, F.D.; Sigman, M.S. J. Am. Chem. Soc. 2016, 138, 15877-15880

185. Production of Fuels and Chemicals from Biomass: Condensation Reactions and Beyond
Wu, L.; Moteki, T.; Gokhale, A.A.; Flaherty, D.W.; Toste, F.D. Chem 2016, 1, 32-58

183. Biomimetic Approach to the Catalytic Enantioselective Synthesis of Flavonoids
Yang, Z.; He, Y.; Toste, F.D. J. Am. Chem. Soc. 2016, 138, 9775-9778

182. Scope and Mechanism of Cooperativity at the Intersection of Organometallic and Supramolecular Catalysis
Levin, M.D.; Kaphan, D.M.; Hong, C.M.; Bergman, R.G.; Raymond, K.N.; Toste, F.D. J. Am. Chem. Soc. 2016, 138, 9682-9693

181. Metal Nanoparticles Catalyzed Selective Carbon-Carbon Bond Activation in the Liquid Phase
Ye, R.; Yuan, B.; Zhao, J.; Ralston, W.T.; Wu, C.Y.; Barin, E.U.; Toste, F.D.; Somorjai, G.A. J. Am. Chem. Soc. 2016, 138, 8533-8537

180. Seven Post-synthetic Covalent Reactions in Tandem Leading to Enzyme-like Complexity within Metal-Organic Framework Crystals
Fracaroli, A.M.; Siman, P.; Nagib, D.A.; Suzuki, M.; Furukawa, H.; Toste, F.D.; Yaghi, O.M. J. Am. Chem. Soc. 2016, 138, 8352-8355

179. Enantioselective Palladium-Catalyzed Oxidative b,b-Fluoroarylation of a,b-Unsaturated Carbonyl Derivatives
Miro, J.; del Pozo, C.; Toste, F.D.; Fustero, S. Angew. Chem. Int. Ed. 2016, 55, 9045-9049

178. Synergistic Effects in Bimetallic Palladium-Copper Catalysts Improve Selectivity in Oxygenate Coupling Reactions
Goulas, K.A.; Sreekumar, S.; Song, Y.; Kharidehal, P.; Gunbas, G.; Dietrich, P.J.; Johnson, G.R.; Wang, Y.C.; Grippo, A.M.; Grabow, L.C.; Gokhale, A.A.; Toste, F.D. J. Am. Chem. Soc. 2016, 138, 6805-6812

177. Isolation and Reactivity of Trifluoromethyl Iodonium Salts
Brantley, J.N.; Samant, A.V.; Toste, F.D. ACS Cent. Sci. 2016, 2, 341-350

175. Enantioselective, Stereodivergent Hydroazidation and Hydroamination of Allenes Catalyzed by Acyclic Diaminocarbene (ADC) Gold(I) Complexes
Khrakovsky, D.A.; Tao, C.; Johnson, M.W.; Thornbury, R.T.; Shevick, S.L.; Toste, F.D. Angew. Chem. Int. Ed. 2016, 55, 6079-6083

172. Phosphonium Formation by Facile Carbon-Phosphorus Reductive Elimination from Gold(III)
Kawai, H.; Wolf, W.J.; DiPasquale, A.G.; Winston, M.S; Toste, F.D. J. Am. Chem. Soc. 2016, 138, 587-593

171. Combining microbial production with chemical upgrading
Goulas, K.A.; Toste, F.D. Current Opinion in Biotechnology 2016, 38, 47-53

169. Visible light-mediated gold-catalysed carbon(sp2) - carbon(sp) cross-coupling
Kim, S.; Rojas-Martin, J.; Toste, F. D. Chem. Sci. 2016, 7, 85-88

168. Protein-like proton exchange in a synthetic host cavity
Hart-Cooper W.M.; Sgarlata,C.; Perrin, C.L.; Bergman, R.G.; Raymond, K.N.; Toste, F. D. Proc. Nat. Acad. Sci. U.S.A. 2015, 112, 15303-15307

167. A supramolecular microenvironment strategy for transition metal catalysis
Kaphan, D.M.; Levin, M.D.; Bergman, R.G.; Raymond, K.N.; Toste, F. D. Science 2015, 350, 1235-1238

165. Upgrading Lignocellulosic Products to Drop-In Biofuels viaDehydrogenative Cross-Coupling and Hydrodeoxygenation Sequence
Sreekumar, S; Balakrishnan, M.; Goulas, K. A.; Gunbas, G.; Gokhale, A. A.; Louie, L.; Grippo, A.; Scown, C. D.; Bell, A. T.; Toste, F. D. ChemSusChem 2015, 8, 2609-2614

164. Palladium-Catalyzed Enantioselective 1,1-Fluoroarylation of Aminoalkenes
He, Y.; Yang, Z.; Thornbury, R. T.; Toste, F. D. J. Am. Chem. Soc. 2015, 137, 12207-12210

163. Supramolecular Ga4L612- Cage Photosensitizes 1,3-Rearrangement of Encapsulated Guest via Photoinduced Electron Transfer
Dalton, D. M.; Ellis, S. R.; Nichols, E. M.; Mathies, R. A.; Toste, F. D.; Bergman; R. G.; Raymond, K. N. J. Am. Chem. Soc. 2015, 137, 10128-10131

162. Enabling New Modes of Reactivity via Constrictive Binding in a Supramolecular-Assembly-Catalyzed Aza-Prins Cyclization
Kaphan, D. M.; Toste, F. D.; Bergman; R. G.; Raymond, K. N. J. Am. Chem. Soc. 2015, 137, 9202-9205

161. Gold(I)-catalyzed enantioselective [3+2] and [3+3] cycloaddition reactions of propargyl acetals/ketals
Navarro, C.; Shapiro, N. D.; Bernasconi, M.; Horibe, T.; Toste, F. D. Tetrahedron 2015, 71, 5800-5805

160. Gold(I)-Catalyzed Desymmetrization of 1,4-Dienes by an Enantioselective Tandem Alkoxylation/Claisen Rearrangement
Zi, W.; Wu, H.; Hongjian, L.; Toste, F. D. Angew. Chem. Int. Ed. 2015, 54, 8529-8532

159. Novel pathways for fuels and lubricants from biomass optimized using life-cycle greenhouse gas assessment
Balakrishnan, M.; Sacia, E. R.; Sreekumar, S.; Gunbas, G.; Gokhale, A. A.; Scown, C. D.; Toste, F. D.; Bell, A. T. Proc. Nat. Acad. Sci. U.S.A. 2015, 112, 7645-7649

158. A Nucleophilic Strategy for Enantioselective Intermolecular alpha-Amination: Access to Enantioenriched a-Arylamino Ketones
Miles, D. H.; Guasch, J.; Toste, F. D. J. Am. Chem. Soc. 2015, 137, 7632-7635

157. Halide-Dependent Mechanisms of Reductive Elimination from Gold(III)
Winston, M. S.; Wolf, W. J.; Toste, F. D. J. Am. Chem. Soc. 2015, 137, 7921-7928

156. A divergent/convergent approach to dolabriferol: the Kornblum-DeLaMare enantiomeric resolution
Gesinski, M. R.; Brenzovich, W. E.; Staben, S. T.; Srinilta, D. J.; Toste, F. D. Tet. Lett. 2015, 56, 3643-3646

155. Silica-Supported Cationic Gold(I) Complexes as Heterogeneous Catalysts for Regio- and Enantioselective Lactonization Reactions
Shu, X.-Z.; Nguyen, S. C.; He, Y.; Oba, F.; Zhang, Q.; Canlas, C.; Somorjai, G. A.; Alivisatos, A. P.; Toste, F. D. J. Am. Chem. Soc. 2015, 137, 7083-7086

154. Highly Selective Condensation of Biomass-Derived Methyl Ketones as a Source of Aviation Fuel
Sacia, E. R.; Balakrishnan, M.; Deaner, M. H.; Goulas, K. A.; Toste, F. D.; Bell, A. T. ChemSusChem 2015, 8, 1726-1736

153. Supramolecular Catalysis in Metal-Ligand Cluster Hosts
Brown, C. J.; Toste, F. D.; Bergman; R. G.; Raymond, K. N. Chem. Rev. 2015, 115, 3012-3035

152. Enantioselective 1,1-Arylborylation of Alkenes: Merging Chiral Anion Phase Transfer with Pd Catalysis
Nelson, H. M.; Williams, B. D.; Miro, J.; Toste, F. D. J. Am. Chem. Soc. 2015, 137, 3213-3216

151. Production of an acetone-butanol-ethanol mixture from Clostridium acetobutylicum and its conversion to high-value biofuels
Sreekumar, S.; Baer, Z. C.; Pazhamalai, A.; Gunbas, G.; Grippo, A.; Blanch, H. W.; Clark, D. G.; Toste, F. D. Nat. Protoc. 2015, 10, 528-537

150. Direct Asymmetric Amination of alpha-Branched Cyclic Ketones Catalyzed by a Chiral Phosphoric Acid
Yang, X.; Toste, F. D. J. Am. Chem. Soc. 2015, 137, 3205-3208

149. Gold(I)-Catalyzed Dearomative Rautenstrauch Rearrangement: Enantioselective Access to Cyclopenta[b]indoles
Zi, W.; Wu, H.; Toste, F. D. J. Am. Chem. Soc. 2015, 137, 3225-3228

148. Catalytic Upgrading of Biomass-Derived Methyl Ketones to Liquid Transportation Fuel Precursors by an Organocatalytic Approach
Sankaranarayanapillai, S.; Sreekumar, S.; Gomes, J.; Grippo, A.; Arab, G. E.; Head-Gordon, M.; Toste, F. D.; Bell, A. T. Angew. Chem. Int. Ed. 2015, 54, 4673-4677

147. Polymer-Encapsulated Metallic Nanoparticles as a Bridge Between Homogeneous and Heterogeneous Catalysis.
Gross, E.; Toste, F. D.; Somorjai, G. A. Catalysis Letters 2015, 145, 126-138

146. A Data-Intensive Approach to Mechanistic Elucidation Applied to Chiral Anion Catalysis.
Neel, A. J.; Milo, A.; Toste, F. D.; Sigman, M. S. Science 2015, 347, 737-743

145. Stable Gold(III) Catalysts by Oxidative Addition of a Carbon-Carbon Bond
Wu, C.-Y.; Horibe, T.; Jacobsen, C. B.; Toste, F. D. Nature 2015, 517, 449-454

143. Engineering Clostridium acetobutylicum for Production of Kerosene and Diesel Blendstock Precursors.
Bormann, S.; Baer, Z. C.; Sreekumar, S.; Kuchenreuther, J. M.; Toste, F. D.; Blanch, H. W.; Clark, D. G. Metab. Eng. 2014, 55, 124-130

142. The Effect of Host Structure on the Selectivity and Mechanism of Supramolecular Catalysis of Prins Cyclizations
Hart-Cooper, W. M.; Zhao, C.; Triano, R. M.; Yaghoubi, P.; Ozores, H.L.; Burford, K. N.; Toste, F. D.; Bergman; R. G.; Raymond, K. N. Chem. Sci. 2015, 6, 1383-1393

140. Enantioselective alpha-Amination Enabled by a BINAM-derived Phase-transfer Catalyst
Nelson, H. M.; Patel, J. S., Shunatona, H. P.; Toste, F. D. Chem. Sci. 2015, 6, 170-173

139. Nucleophilic Substitution Catalyzed by a Supramolecular Cavity Proceeds with Retention of Absolute Stereochemistry
Zhao, C.; Toste, F. D.; Raymond, K. N.; Bergman, R. G. J. Am. Chem. Soc. 2014, 136, 14409-14412

138. An In Situ Directing Group Strategy for Chiral Anion Phase-Transfer Fluorination of Allylic Alcohols
Zi, W.; Wang, Y.-M.; Toste, F. D. J. Am. Chem. Soc. 2014, 136, 12864-12867

137. Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors
Johnson, M. W.; Di Pasquale, A. G.; Bergman, R. G.; Toste, F. D. Organometallics 2014, 33, 4169-4172

136. Chemocatalytic Upgrading of Tailored Fermentation Products Toward Biodiesel
Sreekumar, S.; Baer, Z. C.; Gross, E.; Padmanaban, S.; Goulas, K.; Gunbas, G;, Alayoglu, S.; Blanch, H. W.; Clark, D. S.; Toste, F. D. ChemSusChem 2014, 7, 2445-2448

135. Gold-Catalyzed Allylation of Aryl Boronic Acids:Accessing Cross-Coupling Reactivity with Gold
Levin, M. D.; Toste, F. D. Angew. Chem. Int. Ed. 2014, 53, 6211-6215

134. Photoinitiated Oxidative Addition of CF3I to Gold(I) and Facile Aryl-CF3 Reductive Elimination
Winston, M. S.; Wolf, W. J.; Toste, F. D. J. Am. Chem. Soc. 2014, 136, 7777-7782

133. In-situ IR and X-ray Micro-spectroscopy with High Spatial Resolution of Multistep Organic Transformation in Flow Micro-reactor Catalyzed by Au Nanoclusters
Gross, E.; Shu, X.; Alayoglu, S.; Bechtel, H. A.; Martin, M. C.; Toste, F. D.; Somorjai, G. A. J. Am. Chem. Soc. 2014, 136, 5225-5228

131. Dual Visible Light Photoredox and Gold-Catalyzed Arylative Ring Expansion
Shu, X.; Zhang, M.; He, Y.; Frei, H.; Toste, F. D. J. Am. Chem. Soc. 2014, 136, 5844-5847

130. Chiral Anion Phase Transfer of Aryldiazonium Cations: An Enantioselective Synthesis of C3-Diazenated Pyrroloindolines
Nelson, H. M.; Reisberg, S. H.; Shunatona, H. P.; Patel, J. S.; Toste, F. D.; Angew. Chem. Int. Ed. 2014, 53, 5600-5603

129. Application of Fundamental Organometallic Chemistry to the Development of a Gold-Catalyzed Synthesis of Sulfinate Derivatives
Johnson, M. W.; Bagley, S. W.; Mankad, N. P.; Bergman, R. G.; Mascitti, V.; Toste, F. D.; Angew. Chem. Int. Ed. 2014, 53, 4404-4407

128. Gold-Catalyzed Redox Synthesis of Imidazo[1,2a]pyridine using Pyridine N-Oxide and Alkynes
Talbot, E. P. A.; McKenna, J. M.; Toste, F. D.; Adv. Synth. Catal. 2014, 356, 687-691

127. Asymmetric Palladium-Catalyzed Directed Intermolecular Fluoroarylation of Styrenes
Talbot, E. P. A.; Fernandes, T. A.; McKenna, J. M.; Toste, F. D.; J. Am. Chem. Soc. 2014, 136, 4101-4104

126. Inorganic Micelles as Efficient and Recyclable Micellar Catalyst
Zhang, Q.; Shu, X-Z.; Lucas, J. M.; Toste, F. D.; Somorjai, G. A.; Alivisatos, A. P. Nano. Lett. 2014, 14, 379-383

124. Development of Catalysts and Ligands for Enantioselective Gold Catalysis
Wang, Y-M.; Lackner, A. D.; Toste, F. D. Acc. Chem. Res. 2014, 47, 889-901

123. Chiral Amide Directed Assembly of a Diastereo- and Enantiopure Supramolecular Host and its Application to Enantioselective Catalysis of Neutral Substrates
Zhao, C.; Sun, Q-F.; Hart-Cooper, W. M.; DiPasquale, A. G.; Toste, F. D.; Bergman, R. G.; Raymond, K. N. J. Am. Chem. Soc. 2013, 135, 18802-18805

122. Exceptionally Fast Carbon-Carbon Bond Reductive Elimination from Gold (III)
Wolf, W. J.; Winston, M. S.; Toste, F. D. Nature Chem. 2013, 6, 159-164

120. Vanadium Bisimide Bonding Investigated by X-ray Crystallography, (51)V and (13)C Nuclear Magnetic Resonance Spectroscopy, and V L3,2-Edge X-ray Absorption Near-Edge Structure Spectroscopy
La Pierre, H. S.; Minasian, S. G.; Abubekerov, M.; Kozimor, S. A.; Shuh, D. K.; Tyliszczak, T.; Arnold, J.; Bergman, R. G.; Toste, F. D. Inorg. Chem. 2013, 52, 11650-11660

119. Asymmetric Cross-Dehydrogenative Coupling Enabled by the Design and Application of Chiral Triazole-Containing Phosphoric Acids
Neel, A. J.; Hehn, J. P.; Tripet, P. F.; Toste, F. D. J. Am. Chem. Soc. 2013, 135, 14044-14047

118. Single-Operation Deracemization of 3H-Indolines and Tetrahydroquinolines Enabled by Phase Separation
Lackner, A. D.; Samant, A. V.; Toste, F. D. J. Am. Chem. Soc. 2013, 135, 14090-14093

117. Gold(I)-Catalyzed Enantioselective Carboalkoxylation of Alkynes
Zi, W; Toste, F. D. J. Am. Chem. Soc. 2013, 135, 12600-12603

116. A Combination of Directing Groups and Chiral Anion Phase-transfer Catalysis for Enantioselective Fluorination of Alkenes
Wu, J.; Wang, Y-M.; Drljevic, A.; Rauniyar, V.; Phipps, R. J.; Toste, F. D. Proc. Nat. Acad. Sci. U.S.A. 2013, 110, 13729-13733

115. Gold(I)-catalyzed Enantioselective Bromocyclization Reactions of Allenes
Miles, D.H.; Veguillas, M.; Toste, F. D. Chem. Sci. 2013, 4, 3427-3431

114. Enantioselective Fluoroamination: 1,4-Addition to Conjugated Dienes Using Anionic Phase-Transfer Catalysis
Shunatona, H. P.; Fruh, N.; Wang, Y-M.; Rauniyar, V; Toste, F. D. Angew. Chem. Int. Ed. 2013, 30, 7724-7727

113. Studies on the Vanadium-Catalyzed Nonoxidative Depolymerization of Miscanthus giganteus-Derived Lignin
Chan, J. M. W.; Bauer, S.; Sorek, H.; Sreekumar, S.; Wang, K.; Toste, F. D. ACS Catal. 2013, 3, 1369-1377

112. Enantioselective Cyclization of Enamide-ynes and Application to the Synthesis of the Kopsifoline Core
Corkey, B. K.; Heller, S. T.; Wang, Y. M.; Toste, F. D. Tetrahedron 2013, 69, 5640-5646

111. Asymmetric Catalysis at the Mesoscale: Gold Nanoclusters Embedded in Chiral Self-Assembled Monolayer as Heterogeneous Catalyst for Asymmetric Reactions
Gross, E.; Liu, J. H.; Alayoglu, S.; Marcus, M. A.; Fakra, S. C.; Toste, F. D.; Somorjai, G. A. J. Am. Chem. Soc. 2013, 135, 3881-3886

109. A Supramolecular Approach to Combining Enzymatic and Transition Metal Catalysis
Wang, Z. J.; Clary, K. N.; Bergman, R. G.; Raymond, K. N.;Toste, F. D. Nature Chem. 2013, 5, 100-103

108. Preparation and Reactivity of Terminal Gold(I) Amides and Phosphides
Johnson, M. W.; Shevick, S. L.; Toste, F. D.; Bergman, R. G. Chem. Sci. 2013, 4 1023-1027

106. Integration of Chemical Catalysis with Extractive Fermentation to Produce Fuels
Anbarasan, P.; Baer, Z. C.; Sreekumar, S.; Gross, E.; Binder, J. B.; Blanch, H. W.; Clark, D. S.; Toste, F. D. Nature 2012, 491, 235-239

105. Control of Selectivity in Heterogeneous Catalysis by Tuning Nanoparticle Properties and Reactor Residence Time
Gross, E.; Liu, J.H-C.; Toste, F. D.; Somorjai, G.A. Nature Chem. 2012, 4, 947-952

104. Selective Monoterpene-like Cyclization Reactions Achieved by Water Exclusion from Reactive Intermediates in a Supramolecular Cluster
Hart-Cooper, W.M; Clary, K.N.; Toste, F. D.; Bergman, R. G.; Raymond, K. N. J. Am. Chem. Soc. 2012 134, 17873-17876

103. A Doubly Axially Chiral Phosphoric Acid Catalyst for the Asymmetric Tandem Oxyfluorination of Enamides
Honjo, T; Phipps, R.J.; Rauniyar, V; Toste, F. D. Angew. Chem. Int. Ed. 2012, 51, 9684-9688

102. Enantioselective Halocyclization Using Reagents Tailored for Chiral Anion Phase-Transfer Catalysis
Wang, Y-M.; Wu, J.; Hoong, C.; Rauniyar, V.; Toste, F. D. J. Am. Chem. Soc. 2012, 134, 12928-12931

101. Catalytic Enantioselective Carbon-Carbon Bond Formation Using Cycloisomerization Reactions
Watson, I. D. G.; Toste, F. D. Chem Sci 2012, 3, 2899-2919

100. The Progression of Chiral Anions From Concepts to Applications in Asymmetric Catalysis
Phipps, R. J.; Hamilton, G. L.; Toste, F. D. Nature Chem. 2012, 4, 603-614

98. Asymmetric Fluorination of Enamides: Access to α-Fluoroimines Using an Anionic Chiral Phase-Transfer Catalyst
Phipps, R. J.; Hiramatsu, K.; Toste, F. D.; J. Am. Chem. Soc. 2012, 134, 8376-8379

97. Enantioselective Cyclizations of Silyloxyenynes Catalyzed by Cationic Metal Phosphine Complexes
Brazeau, J.F.; Zhang, S.; Colomer, I.; Corkey, B.K.; Toste, F. D.; J. Am. Chem. Soc. 2012, 134, 2742-2749

96. C(sp3)-F reductive elimination from alkylgold(III) fluoride complexes
Mankad, N.; Toste, F. D. Chem. Sci. 2012, 3, 72-76

95. [(TMEDA)Co(NO)2][BPh4]: A Versatile Synthetic Entry Point to Four and Five Coordinate {Co(NO)2}10 complexes Catalyzed by Cationic Metal Phosphine Complexes
Crimmin, M. R.; Rosebrugh, L. E.; Tomson, N. C.; Weyhermuller, T.; Bergman, R. G.; ; Toste, F. D.; Wieghardt, K.; J. Organometallics Chem. 2011, 696 3974-3981

94. Asymmetric Electrophilic Fluorination Using an Anionic Chiral Phase-Transfer Catalyst
Rauniyar, V.; Lackner, A. D.; Hamilton, G. L.; Toste, F. D. Science, 2011, 334, 1681-1684

93. A Step beyond the Feltham-Enemark Notation: Spectroscopic and Correlated ab Initio Computational Support for an
Antiferromagnetically Coupled M(II)-(NO)- Description of Tp*M(NO) (M = Co, Ni)
Tomason, N.C.; Crimmin, M. R.; Petrenko, T.; Rosebrugh, L. E.; Sproules, S.; Boyd, W. C.; Bergman, R. G.; DeBeer, S.; Toste, F. D.; Wieghardt, K. J. Am. Chem. Soc. 2011, 133, 18785-18801

92 Regio- and Enantioselective Hydroamination of Dienes by Gold(I)/Menthol Cooperative Catalysis
Kanno, O.; Kuriyama, W.; Wang, Z. J.; Toste, F. D. Angew. Chem. Int. Ed. 2011, 42 9919-9922

90. Two Metals Are Better Than One in the Gold Catalyzed Oxidative Heteroarylation of Alkenes
Tkatchouk, E.; Mankad, N. P.; Benitez, D.; Goddard, W. A.; Toste, F. D.; J. Am. Chem. Soc. 2011, 133, 14293-14300

89. A Pt-Cluster-Based Heterogeneous Catalyst for Homogeneous Catalytic Reactions: X-ray Absorption Spectroscopy and Reaction Kinetic Studies of Their Activity and Stability against Leaching
Li, Y.; Liu, J. H-C.; Witham, C. A.; Huang, W.; Marcus, M. A.; Fakra, S. C.; Alayoglu, P.; Zhu, Z.; Thompson, C. M.; Arjun, A.; Lee, K.; Gross, E.; Toste, F. D.; Somorjai, G. A.; J. Am. Chem. Soc. 2011, 133, 13527-13533

87. Chiral (Acyclic Diaminocarbene)Gold(I)-Catalyzed Dynamic Kinetic Asymmetric Transformation of Propargyl Esters
Wang, Y-M.; Kuzniewski, C. N.; Rauniyar, V.; Hoong, C.; Toste, F. D.; J. Am. Chem. Soc. 2011, 133, 12972-12975

86. Direct Michael Addition of Alkenes via a Cobalt-Dinitrosyl Mediated Vinylic C-H Functionalization Reaction
Zhao, C.; Toste, F. D.; Bergman, R. G. J. Am. Chem. Soc. 2011, 133, 10787-10789

85. Synthesis of flinderoles B and C by a gold-catalyzed allene hydroarylation
Zeldin, R. M.; Toste, F. D. Chem. Sci. 2011, 2, 1706-1709

84. Tandem cycloisomerization/Suzuki coupling of arylethynyl MIDA boronates
Chan, J. M. W.; Amarante, G. W; Toste, F. D. Tetrahedron 2011, 67, 4306-4312

83. Enantioselective Synthesis of Highly Substituted Furans by a Copper(II)-Catalyzed Cycloisomerization-Indole Addition Reaction
Rauniyar, V.; Wang, Z. J.; Burks, H. E.; Toste, F. D. J. Am. Chem. Soc. 2011, 133, 8486-8489

81. Hydroalkoxylation Catalyzed by a Gold(I) Complex Encapsulated in a Supramolecular Host
Wang, Z. J.; Casey, C. J; Bergman, R. G.; Raymond, K. N.; Toste, F. D. J. Am. Chem. Soc. 2011, 133, 7358-7360

80. Synthesis of [RuCl2(NO)2(THF)] and its Double C-N Bond-Forming Reactions with Alkenes
Crimmin, M. R.; Bergman, R. G.; Toste, F. D. Angew. Chem. Int. Ed. 2011, 50, 4484-4487

79. Phosphoramidite Gold(I)-Catalyzed Diastereo- and Enantioselective Synthesis of 3,4-Substituted Pyrrolidine
Gonzalez, A. Z; Benitez, D.; Thatchouk, E.; Goddard, W. A.; Toste, F. D. J. Am. Chem. Soc. 2011, 133, 5500-5507

78. Z-Selective Semihydrogenation of Alkynes Catalyzed by a Cationic Vanadium Bisimido Complex
La Pierre, H. S.; Arnold, J.; Toste, F. D. Angew. Chem. Int. Ed. 2011, 50, 3900-3903

77. Gold(I)-Catalyzed Diastereo- and Enantioselective 1,3-Dipolar Cycloaddition and Mannich Reactions of Azlactones
Melhado, A. D.; Amarante, G. W. ; Wang, Z. J.; Luparia, M.; Toste, F. D. J. Am. Chem. Soc. 2011, 133, 3517-3527

76. Asymmetric additions to dienes catalysed by a dithiophosphoric acid
Shapiro, N. D.; Rauniyar, V.; Hamilton, G. L.; Wu, J.; Toste, F. D. Nature. 2011, 470, 245-250

75. Highly Active Heterogeneous Palladium Nanoparticle Catalysts for Homogeneous Electrophilic Reactions in Solution
and the Utilization of a Continuous Flow Reactor
Huang, W.; Liu, J. H.; Alayoglu, P.; Li, Y.; Witham, C. A.; Tsung, C.; Toste, F. D.; Somorjai, G. A. J. Am. Chem. Soc. 2010, 132, 16771-16773

74. Cobalt-Mediated, Enantioselective Synthesis of C2 and C1 Dienes
Boyd, W. C.; Crimmin, M. R.; Rosebrugh, L. E.; Schomaker, J. M.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2010, 132, 16365-16367

73. Gold-Catalyzed Oxidative Coupling Reactions with Aryltrimethylsilanes
Brenzovitch, W. E.; Brazeau, J. F.; Toste, F. D. Org. Lett. 2010, 12, 4728-4731

72. Mechanistic Study of Gold(I)-Catalyzed Intermolecular Hydroamination of Allenes
Wang, Z. J.; Benitez, D.; Tkatchouk, E.; Goddard, W. A.; Toste, F. D. J. Am. Chem. Soc. 2010, 132, 13064-13071

71. C-C Coupling Reactivity of an Alkylgold(III) Fluoride Complex with Arylboronic Acids
Mankad, N.; Toste, F. D. J. Am. Chem. Soc. 2010, 132, 12959-12861

70. Alkylgold Complexes by the Intramolecular Aminoauration of Unactivated Alkenes
LaLonde, R. L.; Brenzovich, W. E.; Benitez, D.; Tkatchouk, E.; Kelly, K.; Goddard, W. A.; Toste, F. D. Chem. Sci. 2010, 1, 226-233

69. Enantioselective Reduction of Ketones and Imines Catalyzed by (CN-Box)ReV-Oxo Complexes
Nolin, K. A.; Ahn, R. W.; Kobayashi, Y.; Kennedy-Smith, J. J.; Toste, F. D. Chem. Eur. J. 2010, 16, 9555-9562

68. Gold-Catalyzed Intramolecular Aminoarylation of Alkenes: C-C Bond Formation through Bimolecular Reductive Elimination
Brenzovitch, W. E.; Benitez, D.; Lackner, A. D.; Shunatona, H. P.; Tkatchouk, E.; Goddard, W. A.; Toste, F. D. Angew. Chem. Int. Ed. 2010, 49, 5519-5512

67. Gold-Catalyzed Three-Component Coupling: Oxidative Oxyarylation of Alkenes
Melhado, A. D.; Brenzovitch, W. E.; Lackner, A. D; Toste, F. D. J. Am. Chem. Soc. 2010, 132, 8885-8887

66. Gold(I)-Catalyzed Enantioselective Polycyclization Reactions
Sethofer, S. G.; Mayer, T.; Toste, F. D. J. Am. Chem. Soc. 2010, 132, 8276-8277

63. Gold(I)-Catalyzed Enantioselective Synthesis of Pyrazolidines, Isoxazolidines, and Tetrahydrooxazines
Lalonde, R. L.; Wang, J. Z.; Mba, M.; Lackner, A. D.; Toste, F. D. Angew. Chem. Int. Ed. 2010, 49, 598-601

62. Gold(I)-Catalyzed Enantioselective [4 + 2]-Cycloaddition of Allene-dienes
Gonzalez, A. Z.; Toste, F. D. Org. Lett. 2010, 12, 200-204

61. Converting Homogeneous to Heterogeneous in Electrophilic Catalysis Using Monodisperse Metal Nanoparticles
Witham, C. A.; Huang, W.; Tsung, C.; Kuhn, J. N.; Samorjai, G. A.; Toste, F. D. Nature Chem 2010, 2, 36-41

60. On the Impact of Steric and Electronic Properties of Ligands on Gold(I)-Catalyzed Cycloaddition Reactions
Benitez, D.; Tkatchouk, E.; Gonzalez, A. Z; Goddard, W. A.; Toste, F. D. Org. Lett. 2009, 11, 4798

59. A Bonding Model for Gold(I) Carbene Complexes
Benitez, D.; Shapiro, N. D.; Tkatchouk, E.; Wang, Y.; Goddard, W. A.; Toste, F. D. Nature Chem. 2009, 1, 482

58. Gold-Catalyzed [3+3]-Annulation of Azomethine Imines with Propargyl Esters
Shapiro, N. D.; Shi, Y.; Toste, F. D. J. Am. Chem. Soc. 2009, 131, 11654-11655

57. Cobalt-Mediated [3 + 2]-Annulation Reaction of Alkenes with α,β-Unsaturated Ketones and Imines
Schomaker, J. M.; Toste, F. D.; Bergman, R. G. Org. Lett. 2009, 11, 3698-3700

56. Gold(I)-Catalyzed Enantioselective Ring Expansion of Allenylcyclopropanols
Kleinbeck, F.; Toste, F. D. J. Am. Chem. Soc. 2009, 131, 9178-9179

55. Ligand-Controlled Access to [4 + 2] and [4 + 3] Cycloadditions in Gold-Catalyzed Reactions of Allene-Dienes
Mauleon, P.; Zeldin, R. M.; Gonzalez, A.Z.; Toste, F. D. J. Am. Chem. Soc. 2009, 131, 6348-6349

54. Development of Ruthenium Catalysts for the Enantioselective Synthesis of P-Stereogenic Phosphines via Nucleophilic Phosphido
Intermediates

Chan, V. S.; Chiu, M.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2009, 129, 15122-15123

53. Mechanistic Studies on Au(I)-Catalyzed [3,3]-Sigmatropic Rearrangements using Cyclopropane Probes
Mauleon, P.; Krinsky, J. L.; Toste, F. D. J. Am. Chem. Soc. 2009, 131, 4513-4520

52. Gold(I)-Catalyzed Enantioselective Synthesis of Benzopyrans via Rearrangement of Allylic Oxonium Intermediates
Uemura, M; Watson, I. D. G.; Toste, F. D. J. Am. Chem. Soc. 2009, 131, 3464-3465

51. Au(I)-Catalyzed Cycloisomerization Terminated by sp3 C-H Bond Insertion
Horino, Y.; Yamamoto, T.; Ueda, K.; Kuroda, S.; Toste, F. D. J. Am. Chem. Soc. 2009, 131, 2809-2811

50. Asymmetric Synthesis of Medium-Sized Rings by Intramolecular Au(I)-Catalyzed Cyclopropanation
Watson, I. D. G.; Ritter, S.; Toste, F. D. J. Am. Chem. Soc. 2009, 131, 2056-2057

49. Chiral Anion-Mediated Asymmetric Ring Opening of meso-Aziridinium and Episulfonium Ions
Hamilton, G. L.; Kanai, T.; Toste, F. D. J. Am. Chem. Soc. 2008, 130, 14984-14986

48. Au(I)-Catalyzed Ring Expanding Cycloisomerizations: Total Synthesis of Ventricosene
Sethofer, S. G.; Staben, S. T.; Hung, O. Y.; Toste, F. D. Org. Lett. 2008, 10, 4315-4318

47. Ligand Effects in Homogeneous Au Catalysis
Gorin, D. J.; Sherry, B. D.; Toste, F. D. Chem. Rev. 2008, 3351-3378

46. Synthesis of Azepines by a Gold-Catalyzed Intermolecular [4 + 3]-Annulation
Shapiro, N. D.; Toste, F. D. J. Am. Chem. Soc. 2008, 130, 9244-9245

45. Synthesis of (-)-Octalactin A by a Strategic Vanadium-Catalyzed Oxidative Kinetic Resolution
Radosevich, A. T.; Chan, V. S.; Shih, H.; Toste, F. D. Angew. Chem. Int. Ed. 2008, 47, 3755-3758

44. Gold-Catalyzed Cycloisomerization of 1,5-Allenynes via Dual Activation of an Ene Reaction
Cheong, P. H.; Morganelli, P.; Luzung, M. R.; Houk, K. N.; Toste, F. D. J. Am. Chem. Soc. 2008, 130, 4517-4526

43. Fluorenes and Styrenes by Au(I)-Catalyzed Annulation of Enynes and Alkynes
Gorin, D. J.; Watson, I. D. G.; Toste, F. D. J. Am. Chem. Soc. 2008, 130, 3736-3737

42. Cobalt Dinitrosoalkane Complexes in the C-H Functionalization of Olefins
Schomaker, J. M.; Boyd, W. C.; Stewart, I. C.; Toste, F. D.; Bergman, R. G. J. Am. Chem. Soc. 2008, 130, 3777-3779

41. Synthesis and Structural Characterization of Isolable Phosphine Coinage Metal π-Complexes
Shapiro, N. D.; Toste, F. D. Proc. Nat. Acad. Sci. U.S.A. 2008, 105, 2779-2782

40. Analysis of an Unprecedented Mechanism for the Catalytic Hydrosilylation of Carbonyl Compounds
Nolin, K. A.; Krumper, J. R.; Pluth M. D.; Bergman, R. D.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 14684-14696

39. Pd-Catalyzed Dynamic Kinetic Enantioselective Arylation of Silylphosphines
Chan, V. S.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 15122-15123

38. Au(I)-Catalyzed Enantioselective 1,3-Dipolar Cycloadditions of Munchnones with Electron-Deficient Alkenes
Melhado, A. D.; Luparia, M.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 12638-12639

37. Gold(I)-Catalyzed [2 + 2]-Cycloaddition of Allenenes
Luzung, M. R.; Mauleon, P.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 12402-12403

36. A Powerful Chiral Counterion Strategy for Asymmetric Transition Metal Catalysis
Hamilton, G. L.; Kang, E. J.; Mba, M.; Toste, F. D. Science 2007, 317, 496-499

35. Gold(I)-Catalyzed Oxidative Rearrangements
Witham, C. A.; Mauleon, P.; Shapiro, N. D.; Sherry, B. D.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 5838-5839

34. Total Synthesis of (+)-Fawcettimine
Linghu, X.; Kennedy-Smith, J. J.; Toste, F. D. Angew. Chem. Int. Ed. 2007, 46, 7671-7673

33. Review: Relativistic Effects in Homogeneous Gold Catalysis
Gorin, D.J.; Toste, F. D. Nature 2007, 446, 395.

32. Rearrangement of Alkynyl Sulfoxides Catalyzed by Gold(I) Complexes
Shapiro, N. D.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 4160-4161.

31. Palladium-Catalyzed Enantioselective Cyclization of Silyloxy-1,6-Enynes
Corkey, B. K.; Toste, F. D. J. Am. Chem. Soc. 2007, 129,2764-2765.

30. Gold(I)-Catalyzed Enantioselective Intramolecular Hydroamination of Allenes
LaLonde, R. L.; Sherry, B. D.; Kang, E. J.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 2452-2453.

29. Gold(I)-Catalyzed Synthesis of Functionalized Cyclopentadienes
Lee, J. H.; Toste, F. D. Angew. Chem. Int. Ed. 2007, 46, 912-914.

28. Synthesis of Benzonorcaradienes by Gold(I)-Catalyzed [4+3] Annulation
Gorin, D. J; Dube, P.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 14480-14481.

27. Enantioselective Synthesis of γ-Hydroxyenones by Chiral Base-Catalyzed Kornblum DeLaMare Rearrangement
Staben, S. T.; Linghu, X.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 12658-12659.

26. Synthesis of Indenyl Ethers by Gold(I)-Catalyzed Intramolecular Carboalkoxylation of Alkynes
Dube, P.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 12062-12063.

25. Stereoselective Synthesis of Vinylsilanes by a Gold(I)-Catalyzed Acetylenic Sila-Cope Rearrangement
Horino, Y.; Luzung, M. R.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 11364-11365.

24. Gold(I)-Catalyzed Cyclizations of Silyl Enol Ethers: Application to the Synthesis of (+)-Lycopladine A
Staben, S. T.; Kennedy-Smith, J. J.; Huang, D.; Corkey, B. K.; Lalonde, R. L.; Toste, F. D. Angew. Chem. Int. Ed. 2006, 45, 5991-5994.

23. Gold(I)-Catalyzed Synthesis of Dihydropyrans
Sherry, B. D; Maus, L.; Laforteza, B. N.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 8132-8133.

22. Synthesis of Aromatic Ketones by a Transition Metal-Catalyzed Tandem Sequence
Zhao, J.; Hughes, C. O.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 7436-7437.

21. Enantioselective Synthesis of Cyclic Ethers through a Vanadium-Catalyzed Resolution/Oxidative Cyclization
Blanc, A.; Toste, F. D. Angew. Chem. Int. Ed. 2006, 45, 2096-2099.

20. Asymmetric Catalytic Synthesis of P-Stereogenic Phosphines via a Nucleophilic Ruthenium Phosphido Complex
Chan, V. S.; Stewart, I. C.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 2786-2787.

19. Gold(I)-Catalysed Stereoselective Olefin Cyclopropanation
Johansson, M. J.; Gorin, D. J.; Staben, S. T.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 18002-18003.

18. Living Ring-Opening Polymerization of N-Sulfonylaziridines: Synthesis of High Molecular Weight Linear Polyamines
Stewart, I. C.; Lee, C. C.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 17616-17617.

17. Catalytic Enantioselective Conia-Ene Reaction
Corkey, B. K.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 17168-17169.

16. Enantioselective Reduction of Imines Catalyzed by a Rhenium(V)-Oxo Complex
Nolin, K. A.; Ahn, R. W.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 12462-12463.

15. Gold(I)-Catalyzed Intramolecular Acetylenic Schmidt Reaction
Gorin, D. J.; Davis, N. R.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 11260-11261.

14. Gold(I)-Catalyzed Ring Expansion of Cyclopropanols and Cyclobutanols
Markham, J. P.; Staben, S. T.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 9708-9709.

13. A Re(V)-Catalyzed C-N Bond-Forming Route to Human Lipoxygenase Inhibitors
Ohri, R. V.; Radosevich, A. T.; Hrovat, K. J.; Musich, C.; Huang, D.; Holman, T. R.; Toste, F. D. Org. Lett. 2005, 7, 2501-2504.

12. Synthesis of 2-Cyclopentenones by Gold(I)-Catalyzed Rautenstrauch Rearrangement
Shi, X.; Gorin, D. J.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 5802-5803.

11. Vanadium-Catalyzed Asymmetric Oxidation of α-Hydroxy Esters Using Molecular Oxygen as Stoichiometric Oxidant
Radosevich, A. T.; Musich, C.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 1090-1091.

10. Gold(I)-Catalyzed Propargyl Claisen Rearrangement
Sherry, B. D.; Toste, F. D. J. Am. Chem. Soc. 2004, 126, 15978-15979.

9. Gold(I)-Catalyzed 5-endo-dig Carbocyclization of Acetylenic Dicarbonyl Compounds
Staben, S. T.; Kennedy-Smith, J. J.; Toste, F. D. Angew. Chem. Int. Ed. 2004, 43, 5350-5352.

8. Catalytic Isomerization of 1,5-Enynes to Bicyclo[3.1.0]hexenes
Luzung, M. R.; Markham, J. P.; Toste, F. D. J. Am. Chem. Soc. 2004, 126, 10858-10859.

7. Rhenium-Catalyzed Aromatic Propargylation
Kennedy-Smith, J. J.; Young, L. A.; Toste, F. D. Org. Lett. 2004, 6, 1325-1327.

6. Gold(I)-Catalyzed Conia-Ene Reaction of β-Ketoesters with Alkynes
Kennedy-Smith, J. J.; Staben, S. T.; Toste, F. D. J. Am. Chem. Soc. 2004, 126, 4526-4527.

5. Rhenium(V)-Catalyzed Synthesis of 2-Deoxy-α-glycosides
Sherry, B. D.; Loy, R. N.; Toste, F. D. J. Am. Chem. Soc. 2004, 126, 4510-4511.

4. Rhenium Catalyzed Coupling of Propargyl Alcohols and Allyl Silanes
Luzung, M. R.; Toste, F. D. J. Am. Chem. Soc. 2003, 125, 15760-15761.

3. Phosphine-catalyzed Hydration and Hydroalkoxylation of Activated Olefins: Use of a Strong Nucleophile to Generate a Strong Base
Stewart, I. C.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2003, 125, 8696-8697.

2. A Mild C-O Bond Formation Catalyzed by a Rhenium-Oxo Complex
Sherry, B. D.; Radosevich, A. T.; Toste, F. D. J. Am. Chem. Soc. 2003, 125, 6076-6077.

1. Reversing the Role of the Metal-oxygen Pi-bond. Chemoselective Catalytic Reductions with a Rhenium(V)-Dioxo Complex
Kennedy-Smith, J. J.; Nolin, K. A.; Gunterman, H. P.; Toste, F. D. J. Am. Chem. Soc. 2003, 125, 4056-4057.