\ The Toste Group :: Members
The Toste Group

137. Synthesis of Stable Gold(III) Pincer Complexes with
Anionic Heteroatom Donors
Johnson, M. W.; Di Pasquale, A. G.; Bergman, R. G.; Toste, F. D. Organometallics 2014, 33, 4169-4172

136. Chemocatalytic Upgrading of Tailored Fermentation
Products Toward Biodiesel
Sreekumar, S.; Baer, Z. C.; Gross, E.; Padmanaban, S.; Goulas, K.; Gunbas, G;, Alayoglu, S.; Blanch, H. W.; Clark, D. S.; Toste, F. D. ChemSusChem 2014, 7, 2445-2448

135. Gold-Catalyzed Allylation of Aryl Boronic Acids:
Accessing Cross-Coupling Reactivity with Gold
Levin, M. D.; Toste, F. D. Angew. Chem. Int. Ed. 2014, 53, 6211-6215

134. Photoinitiated Oxidative Addition of CF3I to Gold(I) and
Facile Aryl-CF3 Reductive Elimination
Winston, M. S.; Wolf, W. J.; Toste, F. D. J. Am. Chem. Soc. 2014, 136, 7777-7782

133. In-situ IR and X-ray Micro-spectroscopy with
High Spatial Resolution of Multistep Organic Transformation
in Flow Micro-reactor Catalyzed by Au Nanoclusters
Gross, E.; Shu, X.; Alayoglu, S.; Bechtel, H. A.; Martin, M. C.; Toste, F. D.; Somorjai, G. A. J. Am. Chem. Soc. 2014, 136, 5225-5228

131. Dual Visible Light Photoredox and Gold-Catalyzed
Arylative Ring Expansion
Shu, X.; Zhang, M.; He, Y.; Frei, H.; Toste, F. D. J. Am. Chem. Soc. 2014, 136, 5844-5847

130. Chiral Anion Phase Transfer of Aryldiazonium Cations:
An Enantioselective Synthesis of C3-Diazenated Pyrroloindolines
Nelson, H. M.; Reisberg, S. H.; Shunatona, H. P.; Patel, J. S.; Toste, F. D.; Angew. Chem. Int. Ed. 2014, 53, 5600-5603

129. Application of Fundamental Organometallic Chemistry to the
Development of a Gold-Catalyzed Synthesis of Sulfinate Derivatives
Johnson, M. W.; Bagley, S. W.; Mankad, N. P.; Bergman, R. G.; Mascitti, V.; Toste, F. D.; Angew. Chem. Int. Ed. 2014, 53, 4404-4407

128. Gold-Catalyzed Redox Synthesis of Imidazo[1,2a]pyridine using
Pyridine N-Oxide and Alkynes
Talbot, E. P. A.; McKenna, J. M.; Toste, F. D.; Adv. Synth. Catal. 2014, 356, 687-691

127. Asymmetric Palladium-Catalyzed Directed Intermolecular
Fluoroarylation of Styrenes
Talbot, E. P. A.; Fernandes, T. A.; McKenna, J. M.; Toste, F. D.; J. Am. Chem. Soc. 2014, 136, 4101-4104

126. Inorganic Micelles as Efficient and Recyclable Micellar Catalyst
Zhang, Q.; Shu, X-Z.; Lucas, J. M.; Toste, F. D.; Somorjai, G. A.; Alivisatos, A. P. Nano. Lett. 2014, 14, 379-383

124. Development of Catalysts and Ligands for Enantioselective
Gold Catalysis
Wang, Y-M.; Lackner, A. D.; Toste, F. D. Acc. Chem. Res. 2014, 47, 889-901

123. Chiral Amide Directed Assembly of a Diastereo- and Enantiopure
Supramolecular Host and its Application to Enantioselective Catalysis of
Neutral Substrates
Zhao, C.; Sun, Q-F.; Hart-Cooper, W. M.; DiPasquale, A. G.; Toste, F. D.; Bergman, R. G.; Raymond, K. N. J. Am. Chem. Soc. 2013, 135, 18802-18805

122. Exceptionally Fast Carbon-Carbon Bond Reductive Elimination
from Gold (III)
Wolf, W. J.; Winston, M. S.; Toste, F. D. Nature Chem. 2013, 6, 159-164

120. Vanadium Bisimide Bonding Investigated by X-ray Crystallography,
(51)V and (13)C Nuclear Magnetic Resonance Spectroscopy,
and V L3,2-Edge X-ray Absorption Near-Edge Structure Spectroscopy
La Pierre, H. S.; Minasian, S. G.; Abubekerov, M.; Kozimor, S. A.; Shuh, D. K.; Tyliszczak, T.; Arnold, J.; Bergman, R. G.; Toste, F. D. Inorg. Chem. 2013, 52, 11650-11660

119. Asymmetric Cross-Dehydrogenative Coupling Enabled by the Design
and Application of Chiral Triazole-Containing Phosphoric Acids
Neel, A. J.; Hehn, J. P.; Tripet, P. F.; Toste, F. D. J. Am. Chem. Soc. 2013, 135, 14044-14047

118. Single-Operation Deracemization of 3H-Indolines and Tetrahydroquinolines
Enabled by Phase Separation
Lackner, A. D.; Samant, A. V.; Toste, F. D. J. Am. Chem. Soc. 2013, 135, 14090-14093

117. Gold(I)-Catalyzed Enantioselective Carboalkoxylation of Alkynes
Zi, W; Toste, F. D. J. Am. Chem. Soc. 2013, 135, 12600-12603

116. A Combination of Directing Groups and Chiral Anion
Phase-transfer Catalysis for Enantioselective Fluorination of Alkenes
Wu, J.; Wang, Y-M.; Drljevic, A.; Rauniyar, V.; Phipps, R. J.; Toste, F. D. Proc. Nat. Acad. Sci. U.S.A. 2013, 110, 13729-13733

115. Gold(I)-catalyzed Enantioselective Bromocyclization Reactions
of Allenes
Miles, D.H.; Veguillas, M.; Toste, F. D. Chem. Sci. 2013, 4, 3427-3431

114. Enantioselective Fluoroamination: 1,4-Addition to Conjugated Dienes
Using Anionic Phase-Transfer Catalysis
Shunatona, H. P.; Fruh, N.; Wang, Y-M.; Rauniyar, V; Toste, F. D. Angew. Chem. Int. Ed. 2013, 30, 7724-7727

113. Studies on the Vanadium-Catalyzed Nonoxidative Depolymerization of
Miscanthus giganteus-Derived Lignin
Chan, J. M. W.; Bauer, S.; Sorek, H.; Sreekumar, S.; Wang, K.; Toste, F. D. ACS Catal. 2013, 3, 1369-1377

112. Enantioselective Cyclization of Enamide-ynes and
Application to the Synthesis of the Kopsifoline Core
Corkey, B. K.; Heller, S. T.; Wang, Y. M.; Toste, F. D. Tetrahedron 2013, 69, 5640-5646

111. Asymmetric Catalysis at the Mesoscale: Gold Nanoclusters
Embedded in Chiral Self-Assembled Monolayer as Heterogeneous Catalyst
for Asymmetric Reactions
Gross, E.; Liu, J. H.; Alayoglu, S.; Marcus, M. A.; Fakra, S. C.; Toste, F. D.; Somorjai, G. A. J. Am. Chem. Soc. 2013, 135, 3881-3886

109. A Supramolecular Approach to Combining Enzymatic and
Transition Metal Catalysis
Wang, Z. J.; Clary, K. N.; Bergman, R. G.; Raymond, K. N.;Toste, F. D. Nature Chem. 2013, 5, 100-103

108. Preparation and Reactivity of Terminal Gold(I) Amides and Phosphides
Johnson, M. W.; Shevick, S. L.; Toste, F. D.; Bergman, R. G. Chem. Sci. 2013, 4 1023-1027

106. Integration of Chemical Catalysis with Extractive Fermentation to
Produce Fuels
Anbarasan, P.; Baer, Z. C.; Sreekumar, S.; Gross, E.; Binder, J. B.; Blanch, H. W.; Clark, D. S.; Toste, F. D. Nature 2012, 491, 235-239

105. Control of Selectivity in Heterogeneous Catalysis by Tuning
Nanoparticle Properties and Reactor Residence Time
Gross, E.; Liu, J.H-C.; Toste, F. D.; Somorjai, G.A. Nature Chem. 2012, 4, 947-952

104. Selective Monoterpene-like Cyclization Reactions Achieved by
Water Exclusion from Reactive Intermediates in a Supramolecular Cluster
Hart-Cooper, W.M; Clary, K.N.; Toste, F. D.; Bergman, R. G.; Raymond, K. N. J. Am. Chem. Soc. 2012 134, 17873-17876

103. A Doubly Axially Chiral Phosphoric Acid Catalyst for the
Asymmetric Tandem Oxyfluorination of Enamides
Honjo, T; Phipps, R.J.; Rauniyar, V; Toste, F. D. Angew. Chem. Int. Ed. 2012, 51, 9684-9688

102. Enantioselective Halocyclization Using Reagents Tailored for
Chiral Anion Phase-Transfer Catalysis
Wang, Y-M.; Wu, J.; Hoong, C.; Rauniyar, V.; Toste, F. D. J. Am. Chem. Soc. 2012, 134, 12928-12931

100. The Progression of Chiral Anions From Concepts to
Applications in Asymmetric Catalysis
Phipps, R. J.; Hamilton, G. L.; Toste, F. D. Nature Chem. 2012, 4, 603-614

98. Asymmetric Fluorination of Enamides: Access to α-Fluoroimines
Using an Anionic Chiral Phase-Transfer Catalyst
Phipps, R. J.; Hiramatsu, K.; Toste, F. D.; J. Am. Chem. Soc. 2012, 134, 8376-8379

97. Enantioselective Cyclizations of Silyloxyenynes
Catalyzed by Cationic Metal Phosphine Complexes
Brazeau, J.F.; Zhang, S.; Colomer, I.; Corkey, B.K.; Toste, F. D.; J. Am. Chem. Soc. 2012, 134, 2742-2749

96. C(sp3)-F reductive elimination from alkylgold(III)
fluoride complexes
Mankad, N.; Toste, F. D. Chem. Sci. 2012, 3, 72-76

95. [(TMEDA)Co(NO)2][BPh4]: A Versatile Synthetic Entry Point
to Four and Five Coordinate {Co(NO)2}10 complexes Catalyzed by
Cationic Metal Phosphine Complexes
Crimmin, M. R.; Rosebrugh, L. E.; Tomson, N. C.; Weyhermuller, T.; Bergman, R. G.; ; Toste, F. D.; Wieghardt, K.; J. Organometallics Chem. 2011, 696 3974-3981

94. Asymmetric Electrophilic Fluorination
Using an Anionic Chiral Phase-Transfer Catalyst

Rauniyar, V.; Lackner, A. D.; Hamilton, G. L.; Toste, F. D. Science, 2011, 334, 1681-1684

93. A Step beyond the Feltham-Enemark Notation:
Spectroscopic and Correlated ab Initio Computational Support for an
Antiferromagnetically Coupled M(II)-(NO)- Description of
Tp*M(NO) (M = Co, Ni)
Tomason, N.C.; Crimmin, M. R.; Petrenko, T.; Rosebrugh, L. E.; Sproules, S.; Boyd, W. C.; Bergman, R. G.; DeBeer, S.; Toste, F. D.; Wieghardt, K. J. Am. Chem. Soc. 2011, 133, 18785-18801

92. Regio- and Enantioselective Hydroamination of Dienes
by Gold(I)/Menthol Cooperative Catalysis
Kanno, O.; Kuriyama, W.; Wang, Z. J.; Toste, F. D. Angew. Chem. Int. Ed. 2011, 42 9919-9922

90. Two Metals Are Better Than One in the Gold Catalyzed
Oxidative Heteroarylation of Alkenes
Tkatchouk, E.; Mankad, N. P.; Benitez, D.; Goddard, W. A.; Toste, F. D.; J. Am. Chem. Soc. 2011, 133, 14293-14300

89. A Pt-Cluster-Based Heterogeneous Catalyst for Homogeneous
Catalytic Reactions: X-ray Absorption Spectroscopy and
Reaction Kinetic Studies of Their Activity and Stability against Leaching
Li, Y.; Liu, J. H-C.; Witham, C. A.; Huang, W.; Marcus, M. A.; Fakra, S. C.; Alayoglu, P.; Zhu, Z.; Thompson, C. M.; Arjun, A.; Lee, K.; Gross, E.; Toste, F. D.; Somorjai, G. A.; J. Am. Chem. Soc. 2011, 133, 13527-13533

87. Chiral (Acyclic Diaminocarbene)Gold(I)-Catalyzed Dynamic
Kinetic Asymmetric Transformation of Propargyl Esters
Wang, Y-M.; Kuzniewski, C. N.; Rauniyar, V.; Hoong, C.; Toste, F. D.; J. Am. Chem. Soc. 2011, 133, 12972-12975

86. Direct Michael Addition of Alkenes via a Cobalt-Dinitrosyl
Mediated Vinylic C-H Functionalization Reaction
Zhao, C.; Toste, F. D.; Bergman, R. G. J. Am. Chem. Soc. 2011, 133, 10787-10789

85. Synthesis of flinderoles B and C by a
gold-catalyzed allene hydroarylation
Zeldin, R. M.; Toste, F. D. Chem. Sci. 2011, 2, 1706-1709

84. Tandem cycloisomerization/Suzuki coupling of
arylethynyl MIDA boronates
Chan, J. M. W.; Amarante, G. W; Toste, F. D. Tetrahedron 2011, 67, 4306-4312

83. Enantioselective Synthesis of Highly Substituted Furans
by a Copper(II)-Catalyzed Cycloisomerization-Indole Addition Reaction
Rauniyar, V.; Wang, Z. J.; Burks, H. E.; Toste, F. D. J. Am. Chem. Soc. 2011, 133, 8486-8489

81. Hydroalkoxylation Catalyzed by a Gold(I) Complex
Encapsulated in a Supramolecular Host
Wang, Z. J.; Casey, C. J; Bergman, R. G.; Raymond, K. N.; Toste, F. D. J. Am. Chem. Soc. 2011, 133, 7358-7360

80. Synthesis of [RuCl2(NO)2(THF)] and its Double
C-N Bond-Forming Reactions with Alkenes
Crimmin, M. R.; Bergman, R. G.; Toste, F. D. Angew. Chem. Int. Ed. 2011, 50, 4484-4487

79. Phosphoramidite Gold(I)-Catalyzed Diastereo- and
Enantioselective Synthesis of 3,4-Substituted Pyrrolidine
Gonzalez, A. Z; Benitez, D.; Thatchouk, E.; Goddard, W. A.; Toste, F. D. J. Am. Chem. Soc. 2011, 133, 5500-5507

78. Z-Selective Semihydrogenation of Alkynes Catalyzed by a
Cationic Vanadium Bisimido Complex
La Pierre, H. S.; Arnold, J.; Toste, F. D. Angew. Chem. Int. Ed. 2011, 50, 3900-3903

77. Gold(I)-Catalyzed Diastereo- and Enantioselective 1,3-Dipolar
Cycloaddition and Mannich Reactions of Azlactones
Melhado, A. D.; Amarante, G. W. ; Wang, Z. J.; Luparia, M.; Toste, F. D. J. Am. Chem. Soc. 2011, 133, 3517-3527

76. Asymmetric additions to dienes catalysed by a
dithiophosphoric acid
Shapiro, N. D.; Rauniyar, V.; Hamilton, G. L.; Wu, J.; Toste, F. D. Nature. 2011, 470, 245-250

75. Highly Active Heterogeneous Palladium Nanoparticle
Catalysts for Homogeneous Electrophilic Reactions in Solution
and the Utilization of a Continuous Flow Reactor
Huang, W.; Liu, J. H.; Alayoglu, P.; Li, Y.; Witham, C. A.; Tsung, C.; Toste, F. D.; Somorjai, G. A. J. Am. Chem. Soc. 2010, 132, 16771-16773

74. Cobalt-Mediated, Enantioselective Synthesis of C2 and C1 Dienes
Boyd, W. C.; Crimmin, M. R.; Rosebrugh, L. E.; Schomaker, J. M.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2010, 132, 16365-16367

73. Gold-Catalyzed Oxidative Coupling Reactions with
Aryltrimethylsilanes
Brenzovitch, W. E.; Brazeau, J. F.; Toste, F. D. Org. Lett. 2010, 12, 4728-4731

72. Mechanistic Study of Gold(I)-Catalyzed Intermolecular
Hydroamination of Allenes
Wang, Z. J.; Benitez, D.; Tkatchouk, E.; Goddard, W. A.; Toste, F. D. J. Am. Chem. Soc. 2010, 132, 13064-13071

71. C-C Coupling Reactivity of an Alkylgold(III) Fluoride Complex
with Arylboronic Acids
Mankad, N.; Toste, F. D. J. Am. Chem. Soc. 2010, 132, 12959-12861

70. Alkylgold Complexes by the Intramolecular Aminoauration of
Unactivated Alkenes
LaLonde, R. L.; Brenzovich, W. E.; Benitez, D.; Tkatchouk, E.; Kelly, K.; Goddard, W. A.; Toste, F. D. Chem. Sci. 2010, 1, 226-233

69. Enantioselective Reduction of Ketones and Imines Catalyzed by
(CN-Box)ReV-Oxo Complexes
Nolin, K. A.; Ahn, R. W.; Kobayashi, Y.; Kennedy-Smith, J. J.; Toste, F. D. Chem. Eur. J. 2010, 16, 9555-9562

68. Gold-Catalyzed Intramolecular Aminoarylation of Alkenes:
C-C Bond Formation through Bimolecular Reductive Elimination
Brenzovitch, W. E.; Benitez, D.; Lackner, A. D.; Shunatona, H. P.; Tkatchouk, E.; Goddard, W. A.; Toste, F. D. Angew. Chem. Int. Ed. 2010, 49, 5519-5512

67. Gold-Catalyzed Three-Component Coupling: Oxidative Oxyarylation
of Alkenes
Melhado, A. D.; Brenzovitch, W. E.; Lackner, A. D; Toste, F. D. J. Am. Chem. Soc. 2010, 132, 8885-8887

66. Gold(I)-Catalyzed Enantioselective Polycyclization Reactions
Sethofer, S. G.; Mayer, T.; Toste, F. D. J. Am. Chem. Soc. 2010, 132, 8276-8277

63. Gold(I)-Catalyzed Enantioselective Synthesis of Pyrazolidines,
Isoxazolidines, and Tetrahydrooxazines
Lalonde, R. L.; Wang, J. Z.; Mba, M.; Lackner, A. D.; Toste, F. D. Angew. Chem. Int. Ed. 2010, 49, 598-601

62. Gold(I)-Catalyzed Enantioselective [4 + 2]-Cycloaddition
of Allene-dienes
Gonzalez, A. Z.; Toste, F. D. Org. Lett. 2010, 12, 200-204

61. Converting Homogeneous to Heterogeneous in Electrophilic
Catalysis Using Monodisperse Metal Nanoparticles
Witham, C. A.; Huang, W.; Tsung, C.; Kuhn, J. N.; Samorjai, G. A.; Toste, F. D. Nature Chem 2010, 2, 36-41

60. On the Impact of Steric and Electronic Properties of Ligands
on Gold(I)-Catalyzed Cycloaddition Reactions
Benitez, D.; Tkatchouk, E.; Gonzalez, A. Z; Goddard, W. A.; Toste, F. D. Org. Lett. 2009, 11, 4798

59. A Bonding Model for Gold(I) Carbene Complexes
Benitez, D.; Shapiro, N. D.; Tkatchouk, E.; Wang, Y.; Goddard, W. A.; Toste, F. D. Nature Chem. 2009, 1, 482

58. Gold-Catalyzed [3+3]-Annulation of Azomethine Imines with
Propargyl Esters
Shapiro, N. D.; Shi, Y.; Toste, F. D. J. Am. Chem. Soc. 2009, 131, 11654-11655

57. Cobalt-Mediated [3 + 2]-Annulation Reaction of
Alkenes with α,β-Unsaturated Ketones and Imines
Schomaker, J. M.; Toste, F. D.; Bergman, R. G. Org. Lett. 2009, 11, 3698-3700

56. Gold(I)-Catalyzed Enantioselective Ring Expansion of
Allenylcyclopropanols
Kleinbeck, F.; Toste, F. D. J. Am. Chem. Soc. 2009, 131, 9178-9179

55. Ligand-Controlled Access to [4 + 2] and [4 + 3]
Cycloadditions in Gold-Catalyzed Reactions of Allene-Dienes
Mauleon, P.; Zeldin, R. M.; Gonzalez, A.Z.; Toste, F. D. J. Am. Chem. Soc. 2009, 131, 6348-6349

54. Development of Ruthenium Catalysts for the Enantioselective
Synthesis of P-Stereogenic Phosphines via Nucleophilic Phosphido
Intermediates

Chan, V. S.; Chiu, M.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2009, 129, 15122-15123

53. Mechanistic Studies on Au(I)-Catalyzed [3,3]-Sigmatropic
Rearrangements using Cyclopropane Probes

Mauleon, P.; Krinsky, J. L.; Toste, F. D. J. Am. Chem. Soc. 2009, 131, 4513-4520

52. Gold(I)-Catalyzed Enantioselective Synthesis of Benzopyrans
via Rearrangement of Allylic Oxonium Intermediates

Uemura, M; Watson, I. D. G.; Toste, F. D. J. Am. Chem. Soc. 2009, 131, 3464-3465

51. Au(I)-Catalyzed Cycloisomerization Terminated by sp3 C-H Bond
Insertion

Horino, Y.; Yamamoto, T.; Ueda, K.; Kuroda, S.; Toste, F. D. J. Am. Chem. Soc. 2009, 131, 2809-2811

50. Asymmetric Synthesis of Medium-Sized Rings by Intramolecular
Au(I)-Catalyzed Cyclopropanation

Watson, I. D. G.; Ritter, S.; Toste, F. D. J. Am. Chem. Soc. 2009, 131, 2056-2057

49. Chiral Anion-Mediated Asymmetric Ring Opening of
meso-Aziridinium and Episulfonium Ions

Hamilton, G. L.; Kanai, T.; Toste, F. D. J. Am. Chem. Soc. 2008, 130, 14984-14986

48. Au(I)-Catalyzed Ring Expanding Cycloisomerizations: Total
Synthesis of Ventricosene

Sethofer, S. G.; Staben, S. T.; Hung, O. Y.; Toste, F. D. Org. Lett. 2008, 10, 4315-4318

47. Ligand Effects in Homogeneous Au Catalysis
Gorin, D. J.; Sherry, B. D.; Toste, F. D. Chem. Rev. 2008, 3351-3378

46. Synthesis of Azepines by a Gold-Catalyzed Intermolecular
[4 + 3]-Annulation

Shapiro, N. D.; Toste, F. D. J. Am. Chem. Soc. 2008, 130, 9244-9245

45. Synthesis of (-)-Octalactin A by a Strategic Vanadium-Catalyzed
Oxidative Kinetic Resolution

Radosevich, A. T.; Chan, V. S.; Shih, H.; Toste, F. D. Angew. Chem. Int. Ed. 2008, 47, 3755-3758

44. Gold-Catalyzed Cycloisomerization of 1,5-Allenynes via Dual
Activation of an Ene Reaction

Cheong, P. H.; Morganelli, P.; Luzung, M. R.; Houk, K. N.; Toste, F. D. J. Am. Chem. Soc. 2008, 130, 4517-4526

43. Fluorenes and Styrenes by Au(I)-Catalyzed Annulation of
Enynes and Alkynes

Gorin, D. J.; Watson, I. D. G.; Toste, F. D. J. Am. Chem. Soc. 2008, 130, 3736-3737

42. Cobalt Dinitrosoalkane Complexes in the C-H Functionalization
of Olefins

Schomaker, J. M.; Boyd, W. C.; Stewart, I. C.; Toste, F. D.; Bergman, R. G. J. Am. Chem. Soc. 2008, 130, 3777-3779

41. Synthesis and Structural Characterization of Isolable Phosphine
Coinage Metal π-Complexes

Shapiro, N. D.; Toste, F. D. Proc. Nat. Acad. Sci. U.S.A. 2008, 105, 2779-2782

40. Analysis of an Unprecedented Mechanism for the Catalytic
Hydrosilylation of Carbonyl Compounds

Nolin, K. A.; Krumper, J. R.; Pluth M. D.; Bergman, R. D.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 14684-14696

39. Pd-Catalyzed Dynamic Kinetic Enantioselective Arylation of
Silylphosphines

Chan, V. S.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 15122-15123

38. Au(I)-Catalyzed Enantioselective 1,3-Dipolar Cycloadditions of
Munchnones with Electron-Deficient Alkenes

Melhado, A. D.; Luparia, M.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 12638-12639

37. Gold(I)-Catalyzed [2 + 2]-Cycloaddition of Allenenes
Luzung, M. R.; Mauleon, P.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 12402-12403

36. A Powerful Chiral Counterion Strategy for Asymmetric Transition
Metal Catalysis

Hamilton, G. L.; Kang, E. J.; Mba, M.; Toste, F. D. Science 2007, 317, 496-499

35. Gold(I)-Catalyzed Oxidative Rearrangements
Witham, C. A.; Mauleon, P.; Shapiro, N. D.; Sherry, B. D.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 5838-5839

34. Total Synthesis of (+)-Fawcettimine
Linghu, X.; Kennedy-Smith, J. J.; Toste, F. D. Angew. Chem. Int. Ed. 2007, 46, 7671-7673

33. Review: Relativistic Effects in Homogeneous Gold Catalysis
Gorin, D.J.; Toste, F. D. Nature 2007, 446, 395.

32. Rearrangement of Alkynyl Sulfoxides Catalyzed by Gold(I)
Complexes

Shapiro, N. D.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 4160-4161.

31. Palladium-Catalyzed Enantioselective Cyclization of
Silyloxy-1,6-Enynes

Corkey, B. K.; Toste, F. D. J. Am. Chem. Soc. 2007, 129,2764-2765.

30. Gold(I)-Catalyzed Enantioselective Intramolecular Hydroamination
of Allenes

LaLonde, R. L.; Sherry, B. D.; Kang, E. J.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 2452-2453.

29. Gold(I)-Catalyzed Synthesis of Functionalized Cyclopentadienes
Lee, J. H.; Toste, F. D. Angew. Chem. Int. Ed. 2007, 46, 912-914.

28. Synthesis of Benzonorcaradienes by Gold(I)-Catalyzed [4+3]
Annulation

Gorin, D. J; Dube, P.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 14480-14481.

27. Enantioselective Synthesis of γ-Hydroxyenones by Chiral Base-
Catalyzed Kornblum DeLaMare Rearrangement

Staben, S. T.; Linghu, X.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 12658-12659.

26. Synthesis of Indenyl Ethers by Gold(I)-Catalyzed Intramolecular
Carboalkoxylation of Alkynes

Dube, P.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 12062-12063.

25. Stereoselective Synthesis of Vinylsilanes by a Gold(I)-Catalyzed
Acetylenic Sila-Cope Rearrangement

Horino, Y.; Luzung, M. R.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 11364-11365.

24. Gold(I)-Catalyzed Cyclizations of Silyl Enol Ethers: Application
to the Synthesis of (+)-Lycopladine A

Staben, S. T.; Kennedy-Smith, J. J.; Huang, D.; Corkey, B. K.; Lalonde, R. L.; Toste, F. D. Angew. Chem. Int. Ed. 2006, 45, 5991-5994.

23. Gold(I)-Catalyzed Synthesis of Dihydropyrans
Sherry, B. D; Maus, L.; Laforteza, B. N.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 8132-8133.

22. Synthesis of Aromatic Ketones by a Transition Metal-Catalyzed
Tandem Sequence

Zhao, J.; Hughes, C. O.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 7436-7437.

20. Asymmetric Catalytic Synthesis of P-Stereogenic Phosphines via a
Nucleophilic Ruthenium Phosphido Complex

Chan, V. S.; Stewart, I. C.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2006, 128, 2786-2787.

19. Gold(I)-Catalysed Stereoselective Olefin Cyclopropanation
Johansson, M. J.; Gorin, D. J.; Staben, S. T.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 18002-18003.

18. Living Ring-Opening Polymerization of N-Sulfonylaziridines: Synthesis
of High Molecular Weight Linear Polyamines

Stewart, I. C.; Lee, C. C.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 17616-17617.

17. Catalytic Enantioselective Conia-Ene Reaction
Corkey, B. K.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 17168-17169.

16. Enantioselective Reduction of Imines Catalyzed by a
Rhenium(V)-Oxo Complex

Nolin, K. A.; Ahn, R. W.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 12462-12463.

15. Gold(I)-Catalyzed Intramolecular Acetylenic Schmidt Reaction
Gorin, D. J.; Davis, N. R.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 11260-11261.

14. Gold(I)-Catalyzed Ring Expansion of Cyclopropanols and
Cyclobutanols

Markham, J. P.; Staben, S. T.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 9708-9709.

13. A Re(V)-Catalyzed C-N Bond-Forming Route to Human
Lipoxygenase Inhibitors

Ohri, R. V.; Radosevich, A. T.; Hrovat, K. J.; Musich, C.; Huang, D.; Holman, T. R.; Toste, F. D. Org. Lett. 2005, 7, 2501-2504.

12. Synthesis of 2-Cyclopentenones by Gold(I)-Catalyzed
Rautenstrauch Rearrangement

Shi, X.; Gorin, D. J.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 5802-5803.

11. Vanadium-Catalyzed Asymmetric Oxidation of α-Hydroxy Esters
Using Molecular Oxygen as Stoichiometric Oxidant

Radosevich, A. T.; Musich, C.; Toste, F. D. J. Am. Chem. Soc. 2005, 127, 1090-1091.

10. Gold(I)-Catalyzed Propargyl Claisen Rearrangement
Sherry, B. D.; Toste, F. D. J. Am. Chem. Soc. 2004, 126, 15978-15979.

9. Gold(I)-Catalyzed 5-endo-dig Carbocyclization of Acetylenic
Dicarbonyl Compounds

Staben, S. T.; Kennedy-Smith, J. J.; Toste, F. D. Angew. Chem. Int. Ed. 2004, 43, 5350-5352.

8. Catalytic Isomerization of 1,5-Enynes to Bicyclo[3.1.0]hexenes
Luzung, M. R.; Markham, J. P.; Toste, F. D. J. Am. Chem. Soc. 2004, 126, 10858-10859.

7. Rhenium-Catalyzed Aromatic Propargylation
Kennedy-Smith, J. J.; Young, L. A.; Toste, F. D. Org. Lett. 2004, 6, 1325-1327.

6. Gold(I)-Catalyzed Conia-Ene Reaction of β-Ketoesters with Alkynes
Kennedy-Smith, J. J.; Staben, S. T.; Toste, F. D. J. Am. Chem. Soc. 2004, 126, 4526-4527.

5. Rhenium(V)-Catalyzed Synthesis of 2-Deoxy-α-glycosides
Sherry, B. D.; Loy, R. N.; Toste, F. D. J. Am. Chem. Soc. 2004, 126, 4510-4511.

4. Rhenium Catalyzed Coupling of Propargyl Alcohols and Allyl Silanes
Luzung, M. R.; Toste, F. D. J. Am. Chem. Soc. 2003, 125, 15760-15761.

3. Phosphine-catalyzed Hydration and Hydroalkoxylation of
Activated Olefins: Use of a Strong Nucleophile to Generate a Strong Base

Stewart, I. C.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2003, 125, 8696-8697.

2. A Mild C-O Bond Formation Catalyzed by a Rhenium-Oxo Complex
Sherry, B. D.; Radosevich, A. T.; Toste, F. D. J. Am. Chem. Soc. 2003, 125, 6076-6077.

1. Reversing the Role of the Metal-oxygen Pi-bond. Chemoselective
Catalytic Reductions with a Rhenium(V)-Dioxo Complex

Kennedy-Smith, J. J.; Nolin, K. A.; Gunterman, H. P.; Toste, F. D. J. Am. Chem. Soc. 2003, 125, 4056-4057.