1. "A Fischer-Type Silylene Complex of Platinum: [trans-(Cy3P)2(H)Pt=Si(SEt)2]BPh4."
S. D. Grumbine, T. D. Tilley, A. L. Rheingold, and F. P. Arnold. J. Am. Chem.
Soc. 1993, 115, 7884.
2. "Base-Free Silylene Complexes Without p-Donor
Stabilization. Molecular Structure of [Cp*(PMe3)2Ru=SiMe2][B(C6F5)4]."
S. K. Grumbine, T. D. Tilley, F. P. Arnold, and A. L. Rheingold. J. Am. Chem.
Soc. 1994, 116, 5495.
3. "Transition Metal-Mediated Redistribution at Silicon: A Bimolecular Mechanism
Involving Silylene Complexes." S. K. Grumbine and T. D. Tilley. J. Am. Chem.
Soc. 1994, 116, 6951.
4. "Synthesis, Structure and Dynamic Studies on Base-Stabilized Silylene Complexes
[(h5-C5Me5)(PMe3)2RuSiX2(NCMe)+]."
S. K. Grumbine, D. A. Straus, T. D. Tilley, and A. L. Rheingold. Polyhedron
1995, 14, 127.
5. "Polysilyl Group Isomerization via Migrations in Rhodium and Iridium Derivatives
(Me3P)3MSi(SiMe3)3." G. P. Mitchell,
T. D. Tilley, G. P. A. Yap, and A. L. Rheingold. Organometallics 1995,
14, 5472.
6. "Migrations in a Polysilyl Complex of Rhodium. Trapping of an Apparent Silylene
Intermediate and Observation of Reversible Si-Si Bond Reductive Elimination."
G. P. Mitchell and T. D. Tilley. Organometallics 1996, 15,
3477.
7. "Reversible Cycloaddition of Isocyanates to Ruthenium Silylene Complexes."
G. P. Mitchell and T. D. Tilley. J. Am. Chem. Soc. 1997, 119,
11236.
8. "Hydrogen Migrations in Rhodium Silyl Complexes: Silylene Intermediates
vs. Oxidative Addition/Reductive Elimination." G. P. Mitchell and T. D. Tilley.
Organometallics 1998, 17, 2912.
9. "Reversible 1,2-Migration of Hydrogen between Platinum and Silicon via Intermediate
Silylene Complexes." G. P. Mitchell and T. D. Tilley. J. Am. Chem. Soc.
1998, 120, 7635.
10. "Generation of a Silylene Complex via the 1,2-Migration of Hydrogen from
Silicon to Platinum." G. P. Mitchell and T. D. Tilley. Angew. Chem. Int.
Ed. 1998, 37, 2524.
11. "Isolation and Characterization of Neutral Platinum Silylene Complexes
of the Type (R3P)2Pt=SiMes2 (Mes = 2,4,6-Trimethylphenyl)."
J. Feldman, G. P. Mitchell, J.-P. Nolte, and T. D. Tilley. J. Am. Chem. Soc.
1998, 120, 11184.
12. "Synthesis and Study of Ruthenium Silylene Complexes of the Type [(h5-C5Me5)(Me3P)2Ru=SiR2]+."
S. K. Grumbine, G. P. Mitchell, D. A. Straus, and T. D. Tilley. Organometallics
1998, 17, 5607.
13. "Silylene Extrusion from a Silane. Direct Conversion of Mes2SiH2
to an Iridium Silylene Dihydride." J. C. Peters, J. D. Feldman, and T. D. Tilley.
J. Am. Chem. Soc. 1999, 121, 9871.
14. "Reactivity of an Osmium Silylene Complex towards Chlorocarbons. Promotion
of Metal Redox Chemistry by a Silylene Ligand, and Relevance to the Mechanism
of the Direct Process." P. W. Wanandi, P. B. Glaser, and T. D. Tilley. J.
Am. Chem. Soc. 2000, 122, 972.
15. "The Mechanism of Silicon-Hydrogen and Carbon-Hydrogen Bond Activation
by Iridium(III): Production of a Silylene Complex, and the First Direct Observation
of Ir(III)/Ir(V) C-H Bond Oxidative Addition and Reductive Elimination." S.
R. Klei, T. D. Tilley, and R. G. Bergman. J. Am. Chem. Soc. 2000,
122, 1816.
16. "Synthesis and Reactivity of Pentamethylcyclopentadienyl Ruthenium Complexes
of the Stable Neutral Silylene Si(tBuNCH=CHNtBu)." J.
M. Dysard and T. D. Tilley. Organometallics 2000, 19, 4726.
17. "An Observable Silene/Silylene Rearrangement in a Cationic Iridium Complex."
S. R. Klei, R. G. Bergman and T. D. Tilley. Organometallics 2001,
19, 4726.
18. "High Oxidation State (Formally d0) Tungsten Silylene Complexes
via Double Si-H Bond Activation." B. V. Mork and T. D. Tilley. J. Am. Chem.
Soc. 2001, 123, 9702.
19. "Reactions of Cp*(PMe3)Ir(Me)OTf with Silanes: Role of Base-Free
Silylene Complexes in Rearrangements of the Resulting Silicon-Based Ligands."
S. R. Klei, T. Don Tilley and R. G. Bergman. Organometallics 2002,
21, 3376.
20. "Activations of Silanes with [PhB(CH2PPh2)3]Ir(H)(h3-C8H13).
Formation of Iridium Silylene Complexes via the Extrusion of Silylenes from
Secondary Silanes R2SiH2." J. D. Feldman, J. C. Peters
and T. D. Tilley. Organometallics 2002, 21, 4065.
21. "Stoichiometric and Catalytic Behavior of Cationic Silyl and Silylene Complexes."
S. R. Klei, T. D. Tilley and R. G. Bergman. Organometallics, 2002,
21, 4648..
22. "Coordinatively and electronically unsaturated tris(trimethylsilyl)silyl
complexes of manganese and iron." R. H. Heyn and T. D. Tilley. Inorg. Chim.
Acta, 2002, 341, 91.
23. "Multiple Bonding Between Silicon and Molybdenum: A Transition Metal
Complex with Considerable Silylyne Character." B. V. Mork and T. D. Tilley.
Angew. Chem. Int. Ed. 2003, 42, 357.
Transition-metal silylene
complexes
24. "Synthesis and study of platinum silylene complexes of the type (R3P)2Pt=SiMes2 (Mes = 2,4,6-trimethylphenyl)." J. D. Feldman, G. P. Mitchell, J.-O. Nolte and T. D. Tilley. Can. J. Chem. 2003, 81, 1127.
25. "Catalytic Hydrosilylation of Alkenes by a Ruthenium Silylene Complex. Evidence for a New Hydrosilylation Mechanism." P. B. Glaser and T. D. Tilley. J. Am. Chem. Soc. 2003, 125, 13640.
26. "Synthesis, Structure, and Reactivity of Osmium Silyl and Silylene Complexes Cp*(Me3P)2OsSiR2X and [Cp*(Me3P)2OsSiR2][B(C6F5)4] ( R= Me, iPr; X = Cl, OTf )." P. B. Glaser, P. W. Wanandi and T. D. Tilley. Organometallics 2004, 23, 693.
27. "Probing the Structure of the Silylene Complex (Cy3P)2Pt=SiMes2. UV-Vis and Preresonance Raman Investigations." S. S. Bukalov, I. A. Garbuzova, L. A. Leites, J. D. Feldman and T. D. Tilley Spectrochim. Acta Part A 2004, 60, 801.
28. "Synthons for Coordinatively Unsaturated Complexes of Tungsten, and their Use for the Synthesis of High Oxidation-State Silylene Complexes." B. V. Mork and T. D. Tilley. J. Am. Chem. Soc. 2004, 126, 4375.
29. "Silylene Hydride Complexes of Molybdenum with Silicon-Hydrogen Interactions. Neutron Structure of (h5-C5Me5)(Me2PCH2CH2PMe2)Mo(H)(SiEt2)." B. V. Mork, T. D. Tilley, A. J. Schultz and J. A. Cowan. J. Am. Chem. Soc. 2004, 126, 10428.
30. "Synthesis and Reactivity of Silyl and Silylene Ligands in the Coordination Sphere of the 14-Electron Fragment Cp*((iPr3P)Os+." P. B. Glaser and T. D. Tilley. Organometallics 2004, 23, 5799.
31. "Transition Metals in Organosilicon Chemistry." In Organosilicon Chemistry VI - From Molecules to Materials, N. Auner and J. Weis, Eds.; Wiley-VCH: Weinheim, Germany, 2005. T. D. Tilley, pp 382-391.
32. "Hydrogen-Substituted Osmium Silylene Complexes: Effect of Charge Localization on Catalytic Hydrosilation" P. G. Hayes, C. Beddie, M. B. Hall, R. Waterman and T. D. Tilley. J. Am. Chem. Soc. 2006, 128, 428.
1. "A Stable h5-Germacyclopentadienyl Complex: (h5-C5Me5)Ru[h5-C4Me4GeSi(SiMe3)3]." W. P. Freeman, T. D. Tilley, A. L. Rheingold and R. L. Ostrander. Angew. Chem. Int. Ed. Engl. 1993, 32, 1744.
2. "Stable Silacyclopentadienyl Complexes of Ruthenium: (h5-C5Me5)Ru[h5-Me4C4Si-Si(SiMe3)3] and X-ray Structure of its Protonated Form." W. P. Freeman, T. D. Tilley, and A. L. Rheingold. J. Am. Chem. Soc. 1994, 116, 8428.
3. "Synthesis and Structure of a Free Germacyclopentadienide Anion: [Li(12-Crown-4)2][C4Me4GeSi(SiMe3)3]." W. P. Freeman, T. D. Tilley, F. P. Arnold, A. L. Rheingold and P. K. Gantzel. Angew. Chem., Int. Ed. Engl. 1995, 34, 1887.
4. "Silolyl Anions and Silole Dianions: X-ray Structure of [K(18-Crown-6)+]2[C4Me4Si2-]." W. P. Freeman, T. D. Tilley, G. A. P. Yap, and A. L. Rheingold. Angew. Chem. Int. Ed. Engl. 1996, 35, 882.
5. "Synthesis and Study of Cyclic p-Systems Containing Silicon and Germanium. The Question of Aromaticity in Cyclopentadienyl Analogues." W. P. Freeman, T. D. Tilley, L. M. Liable-Sands, and A. L. Rheingold. J. Am. Chem. Soc. 1996, 118, 10457.
6. "h5-Silolyl and h5-Germolyl Complexes of d0 Hafnium. Structural Characterization of an h5-Silolyl Complex." J. M. Dysard and T. D. Tilley. J. Am. Chem. Soc. 1998, 120, 8245.
7. "Synthesis and Reactivity of h5-Silolyl, h5-Germolyl and h5-Germole Dianion Complexes of Zirconium and Hafnium." J. M. Dysard and T. D. Tilley. J. Am. Chem. Soc. 2000, 122, 3097.
8. "Hafnium-Rhodium and Hafnium-Iridium Heterobimetallic Complexes Featuring the Bridging Germole Dianion Ligand [GeC4Me4]2-." J. M. Dysard and T. D. Tilley. Organometallics 2000, 19, 2671.
9. "Tantalum-Mediated Substitution at Germanium: A Germolyl-to-Germole Transformation Leading to h4-C4Me4GeMeCl Complexes." J. M. Dysard and T. D. Tilley. Organometallics 2000, 19, 4720.
10. "Silabenzene and Disilabenzene Complexes of Ruthenium." J. M. Dysard, T.
D. Tilley and T. K. Woo. Organometallics 2001, 20, 1195.
11. "Synthesis and Reactivity of h5-Germacyclopentadienyl Complexes of Iron." W. P. Freeman, J. M. Dysard, T. D. Tilley and A. L. Rheingold. Organometallics 2002, 21, 1734.
Coordination chemistry of sila- and germa-aromatic
compounds
1. "The Coordination Polymerization of Silanes to Polysilanes by a "s-Bond
Metathesis" Mechanism. Implications for Linear Chain Growth." T. D. Tilley.
Acc. Chem. Res. 1993, 26, 22.
2. "The Influence of Catalyst Structure on the Dehydropolymerization of Phenylsilane."
T. Imori and T. D. Tilley. Polyhedron 1994, 13, 2231.
3. "Metal-Catalyzed Dehydropolymerization of Secondary Stannanes to High Molecular
Weight Polystannanes." T. Imori, V. Lu, H. Cai and T. D. Tilley. J. Am. Chem.
Soc. 1995, 117, 9931.
4. "Low Band-Gap, s-Conjugated Polymers: Poly(diarylstannanes)."
V. Lu and T. D. Tilley. Macromolecules 1996, 29, 5763.
5. "Synthesis and Reactivity of 16-Electron Hafnocene Silyl Hydride Complexes."
G. L. Casty, C. G. Lugmair, N. S. Radu, T. D. Tilley, J. F. Walzer, and D. Zargarian.
Organometallics 1997, 16, 8.
6. "Synthesis and Reactivity of d0 Bis(imido) Silyl and Germyl Complexes
of Molybdenum and Tungsten." G. L. Casty, T. D. Tilley, G. A. P. Yap and A.
L. Rheingold. Organometallics 1997, 16, 4746.
7. "Carbonylation Chemistry of the Tantalum Silyl Hydride Cp*(2,6-iPr2C6H3N=)Ta[Si(SiMe3)3]H.
The Unexpected Formation of a Ta(V) Carbonyl Complex, and the Complete Reduction
of CO." U. Burckhardt and T. D. Tilley. J. Am. Chem. Soc. 1999,
121,, 6328.
8. "Poly(diaryl)stannanes: Influence of Substituents on the s-s*
Transition Energy." V. Y. Lu and T. D. Tilley. Macromolecules 2000,
33, 2403.
9. "Ditantalum Hydride Complexes with Bridging (2,6-iPr2C6H3)NSiHPh
Silanimine Ligands Resulting from PhSiH3-Imido Ligand Coupling. A
Combined Spectroscopic and Theoretical Investigation." U. Burckhardt, G. L.
Casty, T. D. Tilley, T. K. Woo and U. Rothlisberger. Organometallics
2000, 19, 3830.
10. "Enhanced Reactivity of Cationic vs. Neutral Hafnocene Metal Centers in
Stoichiometric and Catalytic s-Bond Metathesis Reactions
Involving Si-H and Si-C Bonds." A. Sadow and T. D. Tilley. Organometallics,
2001, 20, 4457.
11. "Hafnium imido complexes containing silyl ligands." I. Castillo and T.
D. Tilley. J. Organomet. Chem. 2002, 643-644, 431.
12. "A New Mechanism for Metal-Catalyzed Stannane Dehydrocoupling Based on
a-H-Elimination in a Hafnium Hydrostannyl Complex."
N. R. Neale and T. D. Tilley. J. Am. Chem. Soc. 2002, 124,
3802.
13. "Activation of Arene C-H Bonds by a Cationic Hafnium Silyl Complex Possessing
an a-Agostic Si-H Interaction." A. D. Sadow and T.
D. Tilley. J. Am. Chem. Soc. 2002, 124, 6814.
14. "Reversible Intramolecular Hydride Transfer between Tantalum and an Aromatic
Ring. An h5-Cyclohexadienyl Complex as
a Masked Hydride." J. Gavenonis and T. D. Tilley. J. Am. Chem. Soc. 2002,
124, 8536.
15. "Neutral and Anionic Silyl Hydride Derivatives of the Tantalum Imido Fragment
Cp*(DippN=)Ta (Cp* =h5-C5Me5;
Dipp = 2,6-iPr2C6H3). Reactive
s-Bonds and Intramolecular C-H Bond Activations Involving
the Silyl Ligands." U. Burckhardt, G. L. Casty, J. Gavenonis and T. D. Tilley.
Organometallics 2002, 21, 3108.
16. "Zirconium Amide, Halide, and Alkyl Complexes Supported by Tripodal
Amido Ligands Derived from cis,cis-1,3,5-Triaminocyclohexane."
L. Turculet and T. D. Tilley. Organometallics, 2002, 21,
3961.
Early transition metal chemistry
17. "Tantalum Alkyl and Silyl Complexes of the Bulky (Terphenyl)imido Ligand [2,6-(2,4,6-Me3C6H2)2C6H3N=]2- ([Ar*N=]2-). Generation and Reactivity of [(Ar*N=)(Ar*NH)Ta–(H)(OSO2CF3)], which Reversibly Transfers Hydride to an Aromatic Ring of the Arylamide Ligand." J. Gavenonis and T. D. Tilley. Organometallics, 2002, 21, 5549.
18. "Enhanced Reactivity of Cationic Hafnocene Complexes towards s-Bond Metathesis Reactions. Si–H and Si–C Bond Activations in Stoichiometric and Catalytic Organosilane Conversions." A. D. Sadow and T. D. Tilley. Organometallics, 2003, 22, 3577.
19. "Cationic Hafnium Silyl Complexes and their Enhanced Reactivity in s-Bond Metathesis Processes with Si-H and C-H Bonds." A. D. Sadow and T. D. Tilley. J. Am. Chem. Soc, 2003, 125, 9462.
20. "Synthesis and Reactivity of Alkyl, Hydride, and Silyl Derivatives of the (Terphenyl)imido Fragments Cp*(ArMesN=)Ta (Cp* = h5-C5Me5; ArMes = 2,6-(2,4,6-Me3C6H2)2C6H3) and Cp*(ArTripN=)Ta (ArTrip = 2,6-(2,4,6-iPr3C6H2)2C6H3)." J. Gavenonis and T. D. Tilley. Organometallics, 2004, 23, 31.
21. "Synthesis and reactivity of bis(heptamethylindenyl)yttrium (Ind*2Y) complexes containing alkyl and hydride ligands: crystal structure of Ind*2YCl(THF)." J. Gavenonis and T. D. Tilley. J. Organomet. Chem. 2004, 689, 870.
22. "Synthesis and Reactivity of Tris(imido) Rhenium Complexes Containing Rhenium-Main Group Element Bonds. Silicon-Carbon Bond Activations of PhSiH3 by Silyl Complexes." J. Gavenonis and T. D. Tilley. Inorg. Chem. 2004, 43, 4353.
23. "Reactions of hafnocene stannyl complexes with stannanes: implications for the mechanism of the metal-catalyzed dehydropolymerization of secondary stannanes." N. R. Neale and T. D. Tilley. Tetrahedron 2004, 60, 7247.
24. "Synthesis, Structure, and a-Elimination Chemistry of Hafnocene Triarylstannyl Complexes." N. R. Neale and T. Don Tilley. J. Am. Chem. Soc. 2005, 127, 14745.
25. "Catalytic Antimony-Antimony Bond Formation via Stibinidene Elimination from Zirconocene and Hafnocene Complexes." R. Waterman and T. D. Tilley. Angew. Chem. Intl. Ed., submitted.
1. "Bis(triisopropylsilyl)-o-phenylenediamido Complexes of Titanium
and Zirconium: Investigation of a New Ancillary Ligand." K. Aoyagi, P. K. Gantzel,
K. Kalai, and T. D. Tilley. Organometallics 1996, 15, 923.
2. "Bis(triisopropylsilyl)-o-phenylenediamido Complexes of Tanatalum.
X-ray Structure of (h5-C5Me5)[o-C6H4(NSiiPr3)2]TaCl2".
K. Aoyagi, P. K. Gantzel, and T. D. Tilley. Polyhedron 1996, 15,
4299.
3. "Structure and Reactivity of Chelating Imido-Amido Complexes of Tantalum.
Mechanistic Studies on the Addition of Silanes to Ta=N Multiple Bonds." T. I.
Gountchev and T. D. Tilley. J. Am. Chem. Soc. 1997, 119,
12831.
4. "Yttrium Complexes of the Chelating, C2-Symmetric, Bis(silylamido)biphenyl
Ligand [DADMB]2-, {[6,6'-Me2-(C6H3)2](2,2'-NSiMe2tBu)2}2-."
T. I. Gountchev and T. D. Tilley. Organometallics 1999, 18,
2896.
5. "Hydrosilylation Catalysis by C2-Symmetric Bis(silylamido) Complexes
of Yttrium." T. I. Gountchev and T. D. Tilley. Organometallics 1999,
18, 5661.
6. "Amide, Halide, and Alkyl Zirconium Complexes Supported by Tripodal Amido
Ligands Derived from cis,cis-1,3,5-Triaminocyclohexane." L. Turculet
and T. D. Tilley. Organometallics 2002, 21, 3961.
7. "Synthesis of chelating, C2-symmetric bis(silylamido) complexes of zirconium,
and their activities as olefin polymerization catalysts." T. I. Gountchev and
T. D. Tilley. Inorg. Chim. Acta 2003, 345, 81.
8. "Synthesis and Reactivity of d0 Alkyl, Silyl, and Hydride Complexes
of Titanium and Zirconium Featuring an Aryl-Substituted Tripodal Triamide Ligand
Derived from cis-cis-1,3,5-Triaminocyclohexane." L. Turculet
and T. D. Tilley Organometallics 2004, 23, 1542.
Chelating diamide ancillary ligands for early
metal-catalyzed polymerizations
1. "Autocatalytic Mechanism for s-Bond Metathesis Reactions of (h5-C5Me5)2SmCH(SiMe3)2 with Silicon-Hydrogen Bonds." N. S. Radu and T. D. Tilley. J. Am. Chem. Soc. 1995, 117, 5863.
2. "Samarium-Mediated Redistribution of Silanes and formation of Trinuclear Samarium-Silicon Clusters." N. S. Radu, F. J. Hollander, T. D. Tilley, and A. L. Rheingold. J. Chem. Soc., Chem. Commun. 1996, 2459.
3. "Synthesis of Sm-SiH3 Complexes via s-Bond Metathesis of the Si-C bond of Phenylsilane." I. Castillo and T. D. Tilley. Organometallics 2000, 19, 4733.
4. "Mechanistic Aspects of Samarium-Mediated s-Bond Activations of Arene C-H and Arylsilane Si-C Bonds." I. Castillo and T. D. Tilley. J. Am. Chem. Soc. 2001, 123, 10526.
5. "Organolutetium Complexes in s-Bond Metathesis Reactions Involving Silicon. Catalysts for the Hydrogenolysis of Si-C Bonds." I. Castillo and T. D. Tilley. Organometallics 2001, 20, 5598.
6. "Coordination of 2,2'-Bipyridyl and 1,10-Phenanthroline to Substituted Ytterbocenes: An Experimental Investigation of Spin Coupling in Lanthanide Complexes." M. Schultz, J. M. Boncella, D. J. Berg, T. D. Tilley and R. A. Andersen. Organometallics 2002, 21, 460.
Lanthanide-silicon chemistry
1. "Polymers with Linked Macrocyclic Rings in the Main Chain. Zirconocene Coupling
of 1,8-Cyclotetradecadiyne." S. S. H. Mao and T. D. Tilley. Macromolecules
1996, 29, 6362.
2. "Cross-Conjugated Polymers via Condensation of a Zirconocene Alkynyl(benzyne)
Derivative Generated by Thermolysis of Cp2ZrMe(C6H4CCSiMe3)."
S. S. H. Mao and T. D. Tilley. J. Organomet. Chem. 1996, 521,
425.
3. "A Versatile, Transition Metal-Mediated Route to Blue-Light Emitting Polymers
with Chemically Tunable Luminescent Properties." S. S. H. Mao and T. D. Tilley.
Macromolecules 1997, 30, 5566.
4. "A Zirconocene-Coupling Route to Substituted Poly(p-phenylenedienylene)s:
Bandgap Tuning via Conformational Control." B. L. Lucht, S. S. H. Mao, and T.
D. Tilley. J. Am. Chem. Soc. 1998, 120, 4354.
5. "Zirconocene-Coupling Routes to Conjugated Polymers: Soluble Poly(arylenedienylene)s."
B. L. Lucht and T. D. Tilley. Chem. Commun. 1998, 1645.
6. "General, Efficient Route to Thiophene-1-Oxides and Well-Defined, Mixed
Thiophene-Thiophene-1-Oxide Oligomers." B. Jiang and T. D. Tilley. J. Am.
Chem. Soc. 1999, 121, 9744.
7. "Efficient, Modular Synthetic Route to Oligomers Based on Zirconocene-Coupling.
Properties for Phenylene-Thiophene-1-Oxide and Phenylene-Thiophene-1,1-Dioxide
Chains." M. C. Suh, B. Jiang and T. D. Tilley. Angew. Chem. Int. Ed. Engl.
2000, 39, 2870.
8. "Poly(2,5-diphenylgermole): Incorporation of a Germole Ring into a Conjugated
Polymer." B. L. Lucht, M. A. Buretea, and T. D. Tilley. Organometallics
2000, 19, 3469.
9. "Efficient, High-Yield Route to Long, Functionalized Paraphenylene Oligomers
Containing Perfluorinated Segments, and Their Cyclodimerizations by Zirconocene
Coupling." J. Nitschke and T. D. Tilley. J. Am. Chem. Soc. 2001,
123, 10183.
10. "Reactions of zirconacyclopentadienes with nitrosobenzene. Characterization
of zirconacycle intermediates and formation of N-phenylpyrroles." M. Nakamoto
and T. D. Tilley. Organometallics 2001, 20, 5515.
11. "Regioselective Coupling of Pentafluorophenyl Substituted Alkynes:
Mechanistic Insight into the Zirconocene Coupling of Alkynes and a Facile Route
to Conjugated Polymers Bearing Electron-Withdrawing Pentafluorophenyl Substituents."
S. A. Johnson, F.-Q. Liu, M. C. Suh, S. Zürcher, M. Haufe, S. S. H. Mao
and T. D. Tilley. J. Am. Chem. Soc. 2003, 125, 4199.
Zirconocene-coupling route
to new polymers and oligomers
1. "Poly(ferrocenylenevinylene) from Ring Opening Metathesis Polymerization of ansa-(Vinylene)ferrocene." M. A. Buretea and T. D. Tilley. Organometallics 1997, 16, 1507.
2. "Strained, Ring Tilted Dicarbon-bridged [2]Ferrocenophanes and Ferrocene Revisited: 57Fe Mössbauer Spectroscopic Study of Bonding, Hyperfine Interactions, and Lattice Dynamics." R. H. Herber, K. Temple, I. Manners, M. Buretea, T. D. Tilley. Inorg. Chim. Acta 1999, 287, 152.
3. "An Order-Disorder Phase Transition in Poly(di-n-butylstannane) Observed by UV-vis and Raman Spectroscopy." S. S. Bukalov, L. A. Leites, V. Lu and T. D. Tilley. Macromolecules 2002, 35, 1757.
Transition metal-containing polymers
1. "Coordination Networks Based on Tetrahedral Silane Building Blocks: Influence of the Anion on Structures Adopted by Ag+-Si(p-C6H4CN)4 Arrays." F.-Q. Liu and T. D. Tilley. Inorg. Chem. 1997, 36, 5090.
2. "A coordination network based on d0 transition-metal centers: synthesis and structure of the [4,2]-connected layered compound [(TiCl4)2Si(p-C6H4CN)4]• 1.5C7H8." F.-Q. Liu and T. D. Tilley. J. Chem. Soc., Chem. Commun. 1998, 103.
Coordination networks
1. "Low-Temperature Pyrolytic Transformations of Tri-tert-butoxysiloxy Derivatives
of Aluminum to Aluminosilicate Materials." K. W. Terry, P. K. Ganzel and T.
D. Tilley. Chem. Mater. 1992, 4, 1290.
2. "Cuprous Tris(tert-butoxy)siloxy Complexes and their Thermolytic Conversion
to Copper-Silica and Copper Oxide-Silica Nanocomposites." K. W. Terry, C. G.
Lugmair, P. K. Gantzel, and T. D. Tilley. Chem. Mater. 1996, 8,
274.
3. "Molecular and Polymer Precursor Routes to Manganese-Doped Zinc Orthosilicate
Phosphors". K. Su, T. D. Tilley, and M. J. Sailor. J. Am. Chem. Soc.
1996, 118, 3459.
4. "Zinc Di(tert-butyl)phosphate Complexes as Precursors to Zinc Phosphates.
Manipulation of Zincophosphate Structures." C. G. Lugmair, T. D. Tilley, and
A. L. Rheingold. Chem. Mater. 1997, 9, 339.
5. "Molecular Routes to Metal Oxides and Metal Silicates. Synthesis and Thermal
Decomposition Studies of Eclipsed Mo2[O2Si(OtBu)2]3
and W2(NHMe2)2[O2Si(OtBu)2]2-[OSi(OH)(OtBu)2]2."
K. Su and T. D. Tilley. Chem. Mater. 1997, 9, 588.
6. "Tris(tert-butoxy)siloxy Complexes as Single-Source Precursors to Homogeneous
Zirconia- and Hafnia-Silica Materials. An Alternative to the Sol-Gel Method."
K. W. Terry, C. G. Lugmair and T. D. Tilley. J. Am. Chem. Soc. 1997,
119, 9745.
7. "Hydrolysis of Zirconium and Hafnium Siloxide Complexes. Isolation and Characterization
of Intermediate Aqua Complexes M[OSi(OtBu)3]4(H2O)n
(M = Zr, Hf; n = 1, 2)." C. G. Lugmair and T. D. Tilley. Inorg. Chem.
1998, 37, 764.
8. "Di-tert-buyl Phosphate Complexes of Titanium." C. G. Lugmair and T. D.
Tilley. Inorg. Chem. 1998, 37, 1821.
9. "A Molecular Precursor Route to Active and Selective Vanadia-Silica-Zirconia
Heterogeneous Catalysts for the Oxidative Dehydrogenation of Propane." R. Rulkens
and T. D. Tilley. J. Am. Chem. Soc. 1998, 120, 9959.
10. "Layered Zincophosphate Materials Prepared from a Molecular Zinc Di(tert-butyl)phosphate
Complex in Organic Solvents." C. G. Lugmair and T. D. Tilley. Inorg. Chem.
1998, 37, 6304.
11. "Vanadyl tert-Butoxy Orthosilicate, OV[OSi(OtBu)3]3:
A Model for Isolated Vanadyl Sites on Silica and a Precursor to Vanadia-Silica
Xerogels." R. Rulkens, J. L. Male, K. W. Terry, B. Olthof, A. Khodakov, A. T.
Bell, E. Iglesia, and T. D. Tilley. J. Am. Chem. Soc. 1999, 11,
2966.
12. "Di(tert-butyl)phosphate Complexes of Aluminum. Precursors to Aluminum
Phosphate Xerogels and Thin Films." C. G. Lugmair, T. D. Tilley, and A. L. Rheingold.
Chem. Mater. 1999, 11, 1615.
13. "Titania-Silica Materials from the Molecular Precursor Ti[OSi(OtBu)3]4:
Selective Epoxidation Catalysts." M. P. Coles, C. G. Lugmair, K. W. Terry, and
T. D. Tilley. Chem. Mater. 2000, 12, 122.
14. "Synthesis and Structure of the (Tetrahydroxy)oligosiloxane [(tBuO)3SiOSi(OH)2]2O."
R. Rulkens, M. P. Coles, and T. D. Tilley. Dalton Trans. 2000,
627.
15. "Thermolytic Molecular Precursor Route to Active and Selective Vanadia-Zirconia
Catalysts for the Oxidative Dehydrogenation of Propane." J. L. Male, H. G. Niessen,
A. T. Bell, and T. D. Tilley. J. Catal. 2000, 194, 431.
16. "General Route to Homogeneous, Mesoporous, Multicomponent Oxides Based
on the Thermolytic Transformation of Molecular Precursors in Nonpolar Media."
J. W. Kriesel, M. S. Sander and T. Don Tilley. Adv. Mater. 2001,
13, 331.
17. "A new molecular precursor for magnesia-silica materials." J. W. Kriesel
and T. Don Tilley. J. Mater. Chem. 2001, 11, 1081.
18. "Thermolytic Transformation of Tris(alkoxy)siloxychromium(IV) Single-Source
Molecular Precursors to Catalytic Chromia-Silica Materials." K. L. Fujdala and
T. D. Tilley. Chem. Mater. 2001, 13, 1817
19. "An Efficient, Single-Source Molecular Precursor to Silicoaluminophosphates."
K. L. Fujdala and T. D. Tilley. J. Am. Chem. Soc. 2001, 123,
10133.
20. "Block Copolymer Assisted Synthesis of Mesoporous, Multicomponent Oxides
by Non-hydrolytic, Thermolytic Decomposition of Molecular Precursors in Nonpolar
Media." J. W. Kriesel, M. S. Sander and T. Don Tilley. Chem. Mater. 2001,
13, 3554.
21. "Molecular Design and Synthesis of Heterogeneous and Single-Site, Supported
Catalysts." T. D. Tilley. J. Molec. Catal. A: Chem., in press.
22. "Oxidative Dehydrogenation of Propane over Vanadia-Magnesia Catalysts Prepared
by Thermolysis of OV(OtBu)3 in the Presence of
Nanocrystalline MgO." C. Pak, A. T. Bell and T. D. Tilley. J. Catal.
2002, 206, 49.
23. "New Tris(tert-butoxy)siloxy Complexes of Aluminum and Their Transformation
to Homogeneous Aluminosilicate Materials via Low Temperature Thermolytic Pathways."
C. G. Lugmair, K. L. Fujdala and T. D. Tilley. Chem. Mater. 2002,
14, 888.
24. "New Vanadium Tris(tert-butoxy)siloxy Complexes and Their Thermolytic
Conversions to Vanadia-Silica Materials." K. L. Fujdala and T. D. Tilley. Chem.
Mater. 2002, 14, 1376.
25. "Silica-Supported, Single-Site Titanium Catalysts for Olefin Epoxidation.
A Molecular Precursor Strategy for Control of Catalyst Structure." J. Jarupatrakorn
and T. D. Tilley. J. Am. Chem. Soc. 2002, 124, 8380.
26."Synthesis, Characterization, and Catalytic Performance of Single-Site Iron(III)
Centers on the Surface of SBA-15 Silica." C. Nozaki, C. G. Lugmair, A. T. Bell
and T. D. Tilley. J. Am. Chem. Soc., 2002, 124, 13194.
Molecular precursors to new materials and heterogeneous
catalysts
27. "Tris(tert-butoxy)siloxy Derivatives of Boron, Including the Boronous Acid HOB[OSi(OtBu)3]2 and the Metal (Siloxy)boryloxide Complex Cp2Zr(Me)OB[OSi(OtBu)3]2. A Remarkable Crystal Structure with 18 Independent Molecules in its Asymmetric Unit." K. L. Fujdala, A. G. Oliver, F. J. Hollander and T. D. Tilley. Inorg. Chem. 2003, 42, 1140.
28. "Nonaqueous, Molecular Precursor Route to Hybrid Inorganic/Organic Zirconia-Silica Materials Containing Covalently Linked Organic Bridges." R. L. Brutchey and T. D. Tilley. Chem. Mater. 2003, 15, 1040.
29. "Design and synthesis of heterogeneous catalysts: the thermolytic molecular precursor approach." K. L. Fujdala and T. D. Tilley. J. Catal. 2003, 216, 265.
30. "Thermolytic Molecular Precursor Routes to Cr/Si/Al/O and Cr/Si/Zr/O Catalysts for the Oxidative Dehydrogenation and Dehydrogenation of Propane." K. L. Fujdala and T. D. Tilley. J. Catal. 2003, 218, 123.
31. "Tailoring Properties of Silicon-Containing Oxide Catalysts via the Thermolytic Molecular Precursor Route." In Organosilicon Chemistry V - From Molecules to Materials, N. Auner and J. Weis, Eds.; K. L. Fujdala and T. D. Tilley; Wiley-VCH, Weinheim, Germany, p. 379-388.
32. "Activated Boron Nitride Derived From Activated Carbon." W.-Q. Han, R. Brutchey, T. D. Tilley and A. Zettl. Nano Lett., 2004, 4, 173.
33. "Dimolybdenum(III) Complexes of -OSi(OtBu)3, -O2P(OtBu)2 and -OB[OSi(OtBu)3]2 as Single-Source Molecular Precursors to Molybdenum-Containing, Multi-Component Oxide Materials." K. L. Fujdala and T. D. Tilley. Chem. Mater. 2004, 16, 1035.
34. "Spectroscopic Characterization of Highly Dispersed Vanadia Supported on SBA-15 Silica." C. Hess, J. D. Hoefelmeyer and T. D. Tilley. J. Phys. Chem. B 2004, 108, 9703.
35. "Oxidative Dehydrogenation of Propane over Vanadia Based Catalysts Supported on High-Surface-Area Mesoporous MgAl2O4." O. R. Evans, A. T. Bell and T. D. Tilley. J. Catalysis 2004, 226, 292.
36. "Synthesis and Characterization of {(diene)Rh[m-OSi(OtBu)3]}2, a Model for Silica-Bound Rhodium." J. Jarupatrakorn and T. D. Tilley. Dalton Trans. 2004, 2808.
37. "Atomic Level Control Over Surface Species via a Molecular Precursor Approach: Isolated Cu(I) Sites and Cu Nanoparticles Supported on Mesoporous Silica." K. L. Fujdala, I. J. Drake, A. T. Bell and T. D. Tilley. J. Am. Chem. Soc. 2004, 126, 10864.
38. "Effects of Precursor Composition on the Local Structure of Cu Dispersed on Mesoporous Silica: A Detailed X-ray Absorption Spectroscopy Study." I. J. Drake, K. L. Fujdala, S. Baxamusa, A. T. Bell and T. D. Tilley. J. Phys. Chem. B 2004, 108, 18421.
39. "Synthesis and Reactivity of Ti(III) Tris(tert-butoxy)siloxy Complexes." C. G. Lugmair and T. D. Tilley. Zeitschrift für Naturforschung 2004, 59b, 1540 (special issue to commemorate the 70th birthday of Prof. Hubert Schmidbaur).
40. "Effects of additives on the activity and selectivity of supported vanadia catalysts for the oxidative dehydrogenation of propane." H. X. Dai, L. Chen, T. D. Tilley, E. Iglesia and A. T. Bell. Studies in Surface Science and Catalysis 2004, 147, 679.
41. "Thermolytic Conversion of a Bis(alkoxy)tris(siloxy)tantalum(V) Single-Source Molecular Precursor to Catalytic Tantala-Silica Materials." R. L. Brutchey, C. G. Lugmair, L. O. Schebaum and T. D. Tilley. J. Catal. 2005, 229, 72.
42. "Synthesis and Characterization of MoO[OSi(OtBu)3]4 and MoO2[OSi(OtBu)3]2 (M = Mo, W): Models for Isolated Oxo-Molybdenum and –Tungsten Sites on Silica and Precursors to Molybdenum- and Tungsta-Silica Materials." J. Jarupatrakorn, M. P. Coles and T. D. Tilley. Chem. Mater. 2005, 17, 1818.
43. "Dimethyl carbonate production via the oxidative carbonylation of methanol over Cu/SiO2 catalysts prepared via molecular precursor grafting and chemical vapor deposition approaches." I. J. Drake, K. L. Fujdala, A. T. Bell and T. D. Tilley. J. Catal. 2005, 230, 14.
44. "Liquid phase oxidation of alkylaromatics by an H-atom transfer mechanism with a new heterogeneous CoSBA15 catalyst." R. L. Brutchey, I. J. Drake, A. T. Bell and T. D. Tilley. Chem. Commun. 2005, 3736.
45. "Catalytically Active Titania-Silica Materials Derived from the Dimeric Molecular Precursor [(tBuO)2Ti{m-O2Si[OSi(OtBu)3]2}]2." R. L. Brutchey, B. V. Mork, D. J. Sirbuly, P. Yang and T. D. Tilley. J. Molec. Catal. 2005, 238, 1.
46. "Partial oxidation of methanol over highly dispersed vanadia supported on silica SBA-15." C. Hess, I. J. Drake, J. D. Hoefelmeyer, T. D. Tilley and A. T. Bell. Catal. Lett. 2005, 105, 1.
47. "New Fe/SiO2 Materials Prepared Using Diiron Molecular Precursors: Synthesis, Characterization and Catalysis." A. W. Holland, G. Li, A. M. Shahin, G. J. Long, A. T. Bell and T. D. Tilley. J. Catal. 2005, 235, 150.
48. "Tailored Oxide Materials via Thermolytic Molecular Precursor (TMP) Methods." In Topics in Organometallic Chemistry 16: Surface and Interfacial Organometallic Chemistry and Catalysis, C. Copéret and B. Chaudret, Eds.; Springer-Verlag: Heidelberg, 2005. K. L. Fujdala, R. L. Brutchey and T. D. Tilley, pp 69-115.
49. "Influence of Surface Modification of Ti-SBA15 Catalysts on the Epoxidation Mechanism for Cyclohexene with Aqueous Hydrogen Peroxide." R. L. Brutchey, D. A. Ruddy, L. K. Andersen and T. D. Tilley. Langmuir 2005, 21, 9576.
50. "Synthesis and Characterization of Et2NM{OB[OSi(OtBu)3]2}3 (M = Zr, Hf) Molecular Precursors to Zr/B/Si/O and Hf/B/Si/O Materials." K. L. Fujdala and T. D. Tilley. Z. Anorg. Allg. Chem. 2005, 631, 2619 (special issue to commemorate the 70th birthday of Prof. Herbert Roesky).
51. "Thermolytic Molecular Precursor Route to Site-Isolated Vanadia-Silica Materials and their Catalytic Performance in Methane Partial Oxidation." D. A. Ruddy, N. L. Ohler, A. T. Bell, and T. D. Tilley. J. Catal. 2006, 238, 277.
52. "Single Source Molecular Precursors to Niobia-Silica and Niobium Phosphate
Materials." C. G. Lugmair and T. D. Tilley. Monatshefte für Chemie,
in press (special issue to commemorate the 60th birthday of Prof. Ulrich Schubert).
1. "The Synthesis of Highly Charged Organometallic Dendrimers and their Characterization by Electrospray Mass Spectrometry and Single Crystal X-ray Diffraction." J. Kriesel, S. König, M. A. Freitas, A. G. Marshall, J. Leary, and T. D. Tilley. J. Am. Chem. Soc. 1998, 120, 12207.
2. "Dendrimers as Building Blocks for Nanostructured Materials: Micro- and Mesoporosity in Dendrimer-Based Xerogels." J. Kriesel and T. D. Tilley. Chem. Mater. 1999, 11, 1190.
3. "Synthesis and Chemical Functionalization of High Surface Area Dendrimer-Based Xerogels and Their use as New Catalyst Supports." J. W. Kriesel and T. D. Tilley. Chem. Mater. 2000, 12, 1171.
4. "Carbosilane Dendrimers as Nanoscopic Building Blocks for Hybrid Organic-Inorganic Materials and Catalyst Supports." J. W. Kriesel and T. D. Tilley. Adv. Mater. 2001, 23, 1645.
Dendrimers as building blocks for new materials
1. "Iridium(III) complexes of the new tridentate bis(8-quinolyl)silyl ("NSiN")
ligand." M. Stradiotto, K. L. Fujdala and T. D. Tilley. Chem. Commun.
2001, 1200.
2. "Novel Bis(oxazoline) Pincer Ligands: Formation of Mononuclear Rhodium(II)
Complexes." M. Gerisch, J. R. Krumper, R. G. Bergman and T. D. Tilley. J.
Am. Chem. Soc. 2001, 123, 5818.
3. "Synthesis, Structure and Hydrosilylation Catalysis of a Chiral A-Frame
Rhodium(I) Dimer with Cis-Diphosphite Ligands." S. Ini, A. G. Oliver,
T. D. Tilley and R. G. Bergman. Organometallics 2001, 20,
3839.
4. "Synthesis and Chemistry of the 16-Electron Osmium Complex (h5-C5Me5)(iPr3P)OsBr."
P. B. Glaser and T. D. Tilley. Eur. J. Inorg. Chem. 2001, 2747.
5. "Generation and Reactivity of {(Ethane-1,2-diyl)bis[diisopropylphosphine-kP]}-{[2,4,6-tri(tert-butyl)phenyl]phosphino-kP]}rhodium
([Rh{PH(tBu3C6H2)}(iPr2PCH2CH2PiPr2)]):
Catalytic C-P Bond Formation via Intramolecular C-H/P-H Dehydrogenative Cross-Coupling."
M. Stradiotto, K. L. Fujdala and T. D. Tilley. Helv. Chim. Acta 2001,
84, 2958.
6. "Iridium-Catalyzed H/D Exchange into Organic Compounds in Water." S. R.
Klei, J. T. Golden, T. D. Tilley, and R. G. Bergman. J. Am. Chem. Soc.
2002, 124, 2092.
7. "Structural and Chemical Properties of Zwitterionic Iridium Complexes Featuring
the Tripodal Phosphine Ligand [PhB(CH2PPh2)3]-."
J. D. Feldman, J. C. Peters and T. D. Tilley. Organometallics 2002,
21, 4050.
8. "Iridium(III) and Rhodium(III) Complexes Bearing Chelating Cyclopentadienyl-Phosphine
Ligands as C-H Activation Catalysts for the Deuteration of Hydrocarbons in D2O."
S. R. Klei, T. D. Tilley and R. G. Bergman. Organometallics, 2002,
21, 4905.
9. "Catalytic Functionalization of Hydrocarbons via s-Bond
Metathesis Chemistry: Dehydrosilylation of Methane with a Scandium Catalyst."
A. D. Sadow and T. D. Tilley. Angew. Chem. Int. Ed. 2003, 42,
803.
New ligands and reactive metal centers in transition
metal chemistry and homogeneous catalysis
10. "Homogeneous Catalysis with Methane. A Strategy for the Hydromethylation of Olefins Based on the Nondegenerate Exchange of Alkyl Groups and s-Bond Metathesis at Scandium." A. D. Sadow and T. D. Tilley. J. Am. Chem. Soc. 2003, 125, 7971.
11. "Synthesis and Study of Heterobimetallic Complexes Supported by a Ferrocene-Based Bisphosphine-Diamine Ligand." D. Karshtedt, A. T. Bell and T. D. Tilley. Organometallics 2003, 22, 2855.
12. "Coordinatively and Electronically Unsaturated Zwitterionic Iron Silyl Complexes Featuring the Tripodal Phosphine Ligand [PhB(CH2PiPr2)3]-." L. Turculet, J. D. Feldman and T. D. Tilley. Organometallics, 2003, 22, 4627.
13. "Monomeric Rhodium(II) Catalysts for the Preparation of Aziridines and Enantioselective Formation of Cyclopropanes from Ethyl Diazoacetate at Room Temperature." J. R. Krumper, M. Gerisch, J. M. Suh, R. G. Bergman and T. D. Tilley. J. Org. Chem. 2003, 68, 9705.
14. "Coordination Chemistry and Reactivity of New Zwitterionic Rhodium and Iridium Complexes Featuring the Tripodal Phosphine Ligand [PhB(CH2PiPr2)3]-. Activation of H-H, Si-H, and Ligand B-C Bonds." L. Turculet, J. D. Feldman, and T. D. Tilley. Organometallics 2004, 23, 2488.
15. "The [(h5-C5Me5)(2,2'-bipyridine)Ru]- Anion, and its Use in the Synthesis of Alkyl, Gallyl, and Stannyl Complexes of Ruthenium." B. V. Mork, A. McMillan, H. Yuen and T. D. Tilley. Organometallics 2004, 23, 2855.
16. "Pt-Ag Catalyst System for Hydroarylations with Unactivated Arenes and Olefins." D. Karshtedt, A. T. Bell and T. D. Tilley. Organometallics 2004, 23, 4169.
17. "Unusual Ar-H/Rh-H JHH NMR Coupling in Complexes of Rhodium(III): Experimental Evidence and Theoretical Support for an h1-Arene Structure." J. R. Krumper, M. Gerisch, A. Magistrato, U. Röthlisberger, R. G. Bergman and T. D. Tilley. J. Am. Chem. Soc. 2004, 126, 12492.
18. "C-H Bond Activation by Iridium and Rhodium Complexes: Catalytic Hydrogen-Deuterium Exchange and C-C Bond-Forming Reactions." In Activation and Functionalization of C-H Bonds, ACS Symposium Series 885, K. I. Goldberg and A. S. Goldman, Eds.; American Chemical Society, Washington, 2004. S. R. Klei, K. L. Tan, J. T. Golden, C. M. Yung, R. K. Thalji, K. A. Ahrendt, J. A. Ellman, T. D. Tilley, and R. G. Bergman, Chap. 2, p. 46.
19. "Synthesis and Characterization of Scandium Silyl Complexes of the Type Cp*2ScSiHRR'. s-Bond Metathesis Reactions and Catalytic Dehydrogenative Silation of Hydrocarbons." A. D. Sadow and T. D. Tilley. J. Am. Chem. Soc. 2005, 127, 643.
20. "Synthesis and characterization of scandium complexes with reduced ligands. Crystal structures of Cp*ScI2, [Cp*ScI(bpy)]2, and [Cp*ScCl(bpy)]2" K. A. Tupper and T. D. Tilley. J. Organomet. Chem. 2005, 690, 1689.
21. "Control of Selectivity in the Hydromethylation of Olefins via Ligand Modification in Scandocene Catalysts." F.-G. Fontaine and T. D. Tilley. Organometallics 2005, 24, 4340.
22. "Platinum-Based Catalysts for the Hydroamination of Olefins with Sulfonamides and Weakly Basic Anilines." D. Karshtedt, A. T. Bell and T. D. Tilley. J. Am. Chem. Soc. 2005, 127, 12640.
23. "Rhodium Complexes Containing a Tridentate Bis(8-quinolyl)methylsilyl Ligand: Synthesis and Reactivity." P. Sangtrirutnugul, M. Stradiotto, and T. D. Tilley. Organometallics, in press.
24. "Stoichiometric and Catalytic Arene Activations by Pt Complexes Containing a Bidentate Monoanionic Nitrogen-Based Ligand." D. Karshtedt, J. L. McBee, A. T. Bell and T. D. Tilley. Organometallics, in press.
1. "New Route to Unsaturated Organosilicon Polymers and Macrocycles Based on
Zirconocene-Coupling of 1,4-MeCC(Me2Si)C6H4(SiMe2)CCMe."
S. S. H. Mao and T. Don Tilley. J. Am. Chem. Soc. 1995, 117,
5365.
2. "Efficient, Zirconocene-Mediated Cyclotrimerization and Cyclotetramerization
of Me3SiCCC6H4C6H4CCSiMe3
to Unsaturated Macrocycles." S. S. H. Mao and T. Don Tilley. J. Am. Chem.
Soc. 1995, 117, 7031.
3. "Efficient Zirconocene-Coupling of Silicon-Substituted Diynes to Polymers
and Macrocycles." S. S. H. Mao, F.-Q. Liu and T. D. Tilley. J. Am. Chem.
Soc. 1998, 120, 1193.
4. "A Simple, Efficient Route to Cage Compounds via Zirconocene-Coupling."
F.-Q. Liu, G. Harder, and T. D. Tilley. J. Am. Chem. Soc. 1998,
120, 3271.
5. "Bipyridine-Containing Cyclophanes via Zirconocene-Coupling." J. Nitschke
and T. D. Tilley. J. Org. Chem. 1998, 63, 3673.
6. "New Zirconocene-Coupling Route to Large, Functionalized Macrocycles." J.
R. Nitschke, S. Zürcher and T. D. Tilley. J. Am. Chem. Soc. 2000,
122, 10345.
7. "Efficient Diastereoselective Syntheses of Chiral Macrocycles via Zirconocene-Coupling.
Synthetic Control of Size and Geometry." L. L. Schafer and T. D. Tilley. J.
Am. Chem. Soc. 2001, 123, 2683.
8. "Novel Templating Effect in the Macrocyclization of Functionalized Diynes
via Zirconocene Coupling." J. R. Nitschke and T. D. Tilley. Angew. Chem.,
Int. Ed. Engl. 2001, 40, 2142.
9. "Reactions of zirconacyclopentadienes with nitrosobenzene. Characterization
of zirconacycle intermediates and formation of N-phenylpyrroles." M. Nakamoto
and T. D. Tilley. Organometallics 2001, 20, 5515.
10. "Zirconocene-Mediated, High-Yielding Macrocyclizations of Silyl-Terminated
Diynes." L. L. Schafer, J. R. Nitschke, S. S. H. Mao, F.-Q. Liu, G. Harder,
M. Haufe and T. D. Tilley. Chem. Eur. J. 2002, 8, 74.
11. "Efficient, High-Yield Route to Long, Functionalized Paraphenylene Oligomers
Containing Perfluorinated Segments, and Their Cyclodimerizations by Zirconocene
Coupling." J. Nitschke and T. D. Tilley. J. Am. Chem. Soc. 2001,
123, 10183.
12. "Zirconocene-Mediated, High-Yielding Macrocyclizations of Silyl-Terminated
Diynes." L. L. Schafer, J. R. Nitschke, S. S. H. Mao, F.-Q. Liu, G. Harder,
M. Haufe and T. D. Tilley. Chem. Eur. J. 2002, 8, 74.
13. "Convenient, Zirconocene-Coupling Routes
to Germole- and Thiophene-Containing Macrocycles with Triangular Geometries."
J. R. Nitschke and T. D. Tilley. J. Organomet. Chem. 2003, 666,
15.
1. "Radial Anisotropic Growth of Rhodium Nanoparticles." J. D. Hoefelmeyer,
K. Niesz, G. A. Somorjai and T. D. Tilley. Nano Lett. 2005, 5,
435.
Zirconocene-coupling route to macrocycles and
cages
Nanoparticle synthesis and heterogeneous catalysis