Recent Publications


394. Tan, K.L.; Vasudevan, A.; Bergman, R.G.; Ellman, J.A.; Souers, A.J. "Microwave Assisted C-H Bond Activation: A Rapid Entry into Functionalized Heterocycles" Org. Lett., 2003, 5, 2131-2134.

395. Fox, D.J.; Bergman, R.G. "Synthesis of a First Row Transition Metal Parent Amido Complex and Carbon Monoxide Insertion into the Amide N-H Bond" J. Am. Chem. Soc., 2003, 30, 8984-8985.

396. Taw, F.L.; Bergman, R.G.; Brookhart, M "A Mechanistic Investigation of the Carbon-Carbon Bond Cleavage of Aryl and Alkyl Cyanides Using a Cationic Rh(III) Silyl Complex" J. Am. Chem. Soc., 2003, 125, 9808-9813.

397. Stewart, I.C.; Toste, F.D.; Bergman, R.G. "Phosphine-catalyzed Hydration and Hydroalkoxylation of Activated Olefins: Use of a Strong Nucleophile to Generate a Strong Base" J. Am. Chem. Soc., 2003, 125, 8696-8697.

398. Welch, E.J.; Crawford, N.R.M.; Bergman, R.G.; Long, J.R. "New Routes to Transition Metal-Carbido Species: Synthesis and characterization of the Carbon-Centered Trigonal Prismatic Clusters [W6CCl18]n- (n = 1, 2, 3)" J. Am. Chem. Soc., 2003, 125, 11464-11465.

399. Ackermann, L.; Loy, R.N.; Bergman, R.G. "Use of Group 4 Bis(sulfonamido) Complexes in the Hydroamination of Alkynes and Allenes" J. Am. Chem. Soc., 2003, 125, 11956-11963.

400. Blum, S.A.; Walsh, P.J.; Bergman, R.G. "Epoxide-Opening and Group-Transfer Reactions Mediated by Monomeric Zirconium Imido Complexes" J. Am. Chem. Soc., 2003, 125, 14276-14277.

401. Krumper, J.R.; Gerisch, M.; Suh, J.M.; Tilley, T. Don; Bergman, R.G. "Monomeric Rhodium(II) Catalysts for the Preparation of Aziridines and Enantioselective Formation of Cyclopropanes from Ethyl Diazoacetate at Room Temperature" J. Org. Chem., 2003, 68, 9705-9710.

402. Skaddan, M.B.; Yung, C.M.; Bergman, R.G. "Stoichiometric and Catalytic Deuterium and Tritium Labeling of 'Unactivated' Organic Substrates Cationic Ir(III) Complexes" Org. Lett., 2004, 6, 11-13.

403. Lewis, J.C.; Wiedemann, S.H.; Bergman, R.G.; Ellman, J.A. "Arylation of Heterocycles via Rhodium-catalyzed C-H Bond Functionalization" Org. Lett., 2004, 6, 35-38.

404. Leung, D.; Fiedler, D.; Raymond, K.; Bergman, R.G. "Selective C-H Bond Activation by a Supramolecular Host-Guest assembly" Angew. Chem. 2004, 43, 963-966.

405. Fiedler, D; Pagliero, D; Brumaghim, J.L.; Bergman, R.G.; Raymond, K.N. "Encapsulation of Cationic Ruthenium Complexes into a Chiral Self-Assembled Cage" Inorg. Chem., 2004, 43, 846-848.

406. Taw, F.L.; Bergman, R.G.; Brookhart, M. "Silicon-Hydrogen Bond Activation and Formation of Silane Complexes Using a Cationic Rhodium(III) Complex" Organometallics, 2004, 23, 886-890.

407. Hoyt, H.M.; Michael, F.E.; Bergman, R.G. "C-H Bond Activation of Hydrocarbons by an Imidozirconocene Complex" J. Am. Chem. Soc., 2004, 126, 1018-1019.

408. Cordaro, J.G.; Bergman, R.G. "Elimination of R-H from Iridium Acyl Hydrides without loss of CO. Evidence for the Intervention of Metal Cation/Carbanion Pairs" J. Am. Chem. Soc., 2004, 126, 3432-3433.

409. Fiedler, D.; Leung, D.; Raymond, K.; Bergman, R.G. "Enantioselective Guest-Binding of Cationic Ruthenium Complexes by a Chiral Metal-Ligand Assembly" J. Am. Chem. Soc., 2004, 126, 3674-3675.

410. Fox , D.J.; Bergman, R.G. "Synthesis of an Iron Parent Amido Complex and a Comparison of its Reactivity with the Ruthenium Analog" Organometallics, 2004, 23, 1656-1670.

411. Ruck, R.T.; Bergman, R.G. "Reactions of Imines with Azazirconacyclobutenes and Generation of Electron-Deficient Imidozirconocene Complexes" Organometallics, 2004, 23, 2231-2233.

412. Wiedemann, S.H.; Ellman, J.A.; Bergman, R.G. "Rhodium-Catalyzed Direct C-H Addition of 4,4-Dimethyl-2-oxazoline to Alkenes" Org. Lett., 2004, 6,1685-1687.

413. Thalji, R.K.; Ellman, J.A.; Bergman, R.G. "Highly Efficient and Enantioselective Cyclization of Aromatic Imines via Directed C-H Bond Activation" J. Am. Chem. Soc., 2004, 126, 7192-7193.




S1. Rais, D.; Bergman, R.G. "Synthesis and Reactivity of the Monomeric Late Transition Metal Parent Amido Complex [Cp*Ir(PMe3)(Ph)(NH2)]" Chem. Euro. J. (in press).

S2. Krumper, J.R.; Nolin, K.A.; Bergman, R.G.; Toste, F.D. "A New Mechanism for the Catalyic Hydrosilylation of Carbonyl Compounds: Isolation and X-ray Structure Determination of a Siloxyrhenium(V) Hydride Complex" J. Am. Chem. Soc. submitted for publication.

S3. Ruck, R.T.; Bergman, R.G. "Zirconium-Mediated Conversion of Amides to Nitriles: A Surprising Additive Effect" Angew. Chem. (in press).

S4. Anderson, L.L.; Arnold, J.; Bergman, R.G. "Catalytic Hydroamination of Alkynes and Norbornene with Neutral and Cationic Tantalum Imido Complexes" Org. Lett. (in press).

S5. Krumper, J.R.; Gerisch, M.; Magistrato, A.; Roethlisberger, U.*; Bergman, R.G.*, Tilley, D.T.* " 1-Arene Complexes of Rhodium(III): Experimental Evidence and Theoretical Studies" J. Am. Chem. Soc. (accepted).

S6. Blum, S.A.; Bergman, R.G.* "Nitro and Nitroso Metathesis Reactions with Monomeric Zirconium Imido Complexes" Organometallic(accepted).

S7. Corkey, B.K.; Taw, F.L.; Brookhart, M.*; Bergman, R.G.* "Aromatic and Aldehyde Carbon-Hydrogen Bond Activation at Cationic Rh(III) Centers. Evaluation of Electronic Substituent Effects on Aldehyde Binding and C-H Oxidative Addition" in progress.

S8. Tan, K.L.; Park, S.; Ellman, J.A.*; Bergman, R.G.* "Intermolecular Coupling of Alkenes to Heterocycles via C-H Bond Activation" J. Am. Chem. Soc. submitted for publication.

S9. Krumper, J.R.; Veltheer, J.; Martin, R.L.; Hay, P.J.; Bergman, R.G.* "Synthesis and Reactivity of the Hydrido- and Alkyl-Rhenium Methylidene Complexes Cp*(PMe3)2(R)Re=CH2, R = H, CH3" J. Am. Chem. Soc. submitted for publication.

S10. Yung, C.M.; Skaddan, M.B., Bergman, R.G.* "Stoichiometric and Catalytic H/D Incorporation by Cationic Iridium Complexes: A Common Monohydrido-Iridium Intermediate" J. Am. Chem. Soc. (accepted).

S11. Ruck, R.T.; Bergman, R.G.* "Carboamination: Additions of Imine C=N Bonds Across Alkynes Catalyzed by Imidozirconium Complexes" Angew. Chem. (in press).

S12. Fiedler, D.; Leung, D.; Raymond, K.; Bergman, R.G. "Selective Molecular Recognition, C-H Bond Activation, and Catalysis in Nanoscale Reaction Vessels" Acct. Chem. Res. submitted for publication.

S13. Cordaro, J.G.; Bergman, R.G. "Dissociation of Carbanions from Acyl Iridium Compounds: An Experimental and Computational Investigation" J. Am. Chem. Soc. submitted for publication.

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