“Spatial Resolution of a Type II Heterojunction in a Single Bipolar Molecule,” C. G. Tao, J. B. Sun, X. W. Zhang, R. Yamachika, D. Wegner, Y. Bahri, G. Samsonidze, S. G. Louie, T. D. Tilly, R. A. Segalman and M. F. Crommie, submitted.

“The Nature of Transport Variations in Molecular Heterojunction Electronics,” J. A. Malen, P. Doak, K. Baheti, T. D. Tilley, R. A. Segalman and A. Majumdar, submitted.

“The Relationship Between Morphology and Performance of Donor-Acceptor Rod-Coil Block Copolymer Solar Cells,” Y. Tao, B. McCulloch, S. Kim and R. A. Segalman, Soft Matter, in press.

“Phase Behavior of Polystyrene-block-Poly(2-vinyl pyridine) Copolymers in Selective Ionic Liquid Solvents,” J. M. Virgili, A. Hexemer, J. A. Pople, N. Balsara and R. A. Segalman, Macromolecules; 2009; 42; 4604-4613.

“Synthesis and Self-Assembly of Poly(diethylhexyloxy-p-phenylenevinylene)-b-poly(methyl methacrylate) Rod-Coil Block Copolymers,” C-C Ho, Y-H Lee, C-A Dai, R. A. Segalman and W-F Su; 2009; Macromolecules; 2009; 42(12); 4208-4219.

“Rheological Properties and the Mechanical Signatures of Phase Transitions in Weakly Segregated Rod-Coil Block Copolymers,” B. D. Olsen, N. P. Teclemariam, S. J. Muller, and R. A. Segalman, Soft Matter; 2009; 5(12); 2453-2462.

“Identifying the Length Dependence of Orbital Alignment and Contact Coupling in Molecular Heterojunctions,” J. A. Malen, P. Doak, K. Baheti, T. D. Tilley, R. A. Segalman and A. Majumdar, Nano Lett.; 2009; 9(3); 1164-1169.

“Near-Surface and Internal Lamellar Structure and Orientation in Thin Films of Rod-Coil Block Copolymers,” B. D. Olsen, X. Li, J. Wang and R. A. Segalman, Soft Matter; 2009; 5; 182-192.

“Synthesis and Characterizing of 2,7-bis(pentafluorophenylethynyl) hexafluoroheterofluorenes: New Materials with High Electron Affinities,” K. Geramita, J. McBee, Y. Tao, R. A. Segalman and T. D. Tilley, Chem. Comm. 2008; 41; 5107-5109.

“Self-Assembly of Rod-Coil Block Copolymers and their Application in Electroluminescent Devices,” Y. Tao, B. Ma and R. A. Segalman, Macromolecules; 2008; 41(19); 7152-7159.

“Universalization of the Phase Diagram for a Model Rod-Coil Diblock Copolymer,” B. D. Olsen, M. Shah, V. Ganesan and R. A. Segalman, Macromolecules; 2008; 41(18); 6809-6817.

“Self-Assembly of Rod-Coil Block Copolymers,” B. D. Olsen and R. A. Segalman, Materials Science and Engineering Reports R: Reviews; 2008; 62(2); 37-66.

"MATERIALS SCIENCE: Directing Self-Assembly Toward Perfection" R.A. Segalman, Science 321 (5891), 919 (2008).

"Enhanced Thermopower in PbSe Nanocrystal Quantum Dot Superlattices," R.Y. Wang, J.P. Feser, J.-S. Lee, D.V. Talapin, R.A. Segalman, A. Majumdar, Nanoletters, 2008, 8(8): 2283-2288.

"Square Grains in Asymmetric Rod-Coil Block Copolymers," B.D. Olsen, M.F. Toney, R.A. Segalman, Langmuir, 2008.

" Probing the Chemistry of Molecular Heterojunctions Using Thermoelectricity," K. Baheti, J.A. Malen, P. Doak, P. Reddy, S-Y Jang, T.D. Tilley, A. Majumdar, R.A. Segalman, Nano Lett; 2008; 8(2); 715-719.

"Crystalline Structure in Thin Films of DEH-PPV Homopolymer and PPV-b-PI Rod-Coil Block Copolymers," B.D. Olsen, D. Alcazar, V. Krikorian, M.F. Toney, E.L. Thomas, R.A. Segalman, Macromolecules; 2008; 41(1); 58-66.

" Hierarchical Nanostructure Control in Rod-Coil Block Copolymers with Magnetic Fields." Y. Tao, H. Zohar, B.D. Olsen, and R.A. Segalman, Nano Lett.; 2007; 7(9); 2742-2746.

"Non-Lamellar Phases in Asymmetric Rod-Coil Block Copolymers," B.D. Olsen and R.A. Segalman, Macromolecules; 2007; 40(19); 6922-6929.

"Domain Size Control in Self-Assembling Rod-Coil Block Copolymer and Homopolymer Blends," Y. Tao, B.D. Olsen, V. Ganesan and R.A. Segalman, Macromolecules; 2007; 40(9); 3320-3327.

Thin Film Structure of Symmetric Rod-Coil Block Copolymers.” B.D. Olsen , X. Li, J. Wang and R.A. Segalman, Macromolecules; 2007; 40(9); 3287-3295.

Thermoelectricity in Molecular Junctions,” P. Reddy, S.Y. Jang, R.A. Segalman and A. Majumdar, Science; 2007; 315: 1568-1571.

Analysis of Order Formation in Block Copolymer Thin Films using Resonant Soft X-ray Scattering,” J. Virgili, Y. Tao, J.B. Kortright, N.P. Balsara and R.A. Segalman, Macromolecules; 2007; 40(6); 2092-2099.

Room temperature thermal conductance of alkanedithiol self-assembled monolayers,” R. Wang, R.A. Segalman, and A. Majumdar, Applied Physics Letters; 2006; 89.

"Phase Transitions in Asymmetric Rod-Coil Block Copolymers,” B.D. Olsen, R. A. Segalman, Macromolecules; 2006; 39; 7078-7083.

Interpretation of Stochastic Events in Single Molecule Conductance Measurements,” P. Reddy, S.Y. Jang, A. Majumdar, R.A. Segalman, Nanoletters; 2006; 6; 2362-2367.

Higher order liquid crystallinity in low polydispersity poly(phenylene vinylenes),” B.D. Olsen, S.Y. Jang, J. Luning, and R. A. Segalman, Macromolecules; 2006; 39(13); 4469-4479.

"Structure and Thermodynamics of Weakly Segregated Rod-Coil Block Copolymers," B.D. Olsen and R.A. Segalman, Macromolecules; 2005; 38(24), 10127 - 10137.

"Patterning with Block Copolymer Thin Films,” R.A. Segalman, Materials Science and Engineering Reports R: Reviews; 2005; 48(6); 191-226.

"Solar Cells Based on Diblock Copolymers: A PPV donor block and a fullerene derivatized acceptor block,” R. A. Segalman, C. Brochon, G. Hadziioannou, (Book Chapter in Organic Photovoltaics by Sun and Sariciftci, Marcel-Dekker) 2005.

"Grain Structure in Block Copolymer Thin Films Studied by Guided Wave Depolarized Light Scattering", Garetz, B. A.; Newstein, M. C.; Wilbur, J. D.; Patel, A. J.; Durkee, D. A.; Segalman, R. A.; Liddle, J. A.; Balsara, N. P.; Macromolecules; 2005; 38(10); 4282-4288.

"Polymer Diffusion in Semicrystalline Polymers Using Secondary Ion Mass Spectroscopy,” R. A. Segalman, S. Lustig, E. J. Kramer, Macromolecules; 2004; 37(7); 2613-2617.

"Edge Effects on the Order and Melting of a 2D Array of Block Copolymer Spheres,” R. A. Segalman, A. Hexemer, E. J. Kramer, Physical Review Letters 2003; 91(19); 196101.

Effects of Lateral Confinement on Order in Spherical Domain Block Copolymer Thin Films,” R. A. Segalman, A. Hexemer, E. J. Kramer, Macromolecules, 2003; 36(18); 6831-6839.

Topographic Templating of Islands and Holes in Highly Asymmetric Block Copolymer Films,” R. A. Segalman, K. E. Schaeffer, G. H. Fredrickson, E. J. Kramer, S. Magonov; Macromolecules; 2003; 36(12); 4498-4506.

Ordering and Melting of Block Copolymer Spherical Domains in 2 and 3 Dimensions,” R.A. Segalman, A. Hexemer, R. C. Hayward, E. J. Kramer, Macromolecules; 2003; 36(9); 3272-3288.

Graphoepitaxy of Asymmetric Diblock Copolymers," R.A. Segalman, H. Yokoyama, E.J. Kramer, Advanced Materials 2001, 13, 1152.

Dynamics of Rims and the Onset of Spinodal Dewetting at Liquid/Liquid Interfaces.” R. A. Segalman, P. F. Green, Macromolecules; 1999; 32(3); 801-807.

Robocasting: Rapid Prototyping of Ceramic Slurries.” J. Cesarano, R. A. Segalman, P. Calvert P, Ceramic Industry April 1998; 94-102.


We gratefully acknowledge funding from the following sources:
  • DOE-BES Plastic Electronics Program at LBNL
  • DOE-BES Fuel Cell Program at LBNL
  • DOE-BES Helios Program
  • NSF-CAREER Award
  • NSF-NIRT Program
  • ACS-PRF Program
  • 3M Untenured Faculty Award
  • UC Energy Initiative
  • Hellman Untenured Faculty Award
  • MDV Innovators Award
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