8. New Organometallic Reactions

Hanley, P.S.; Hartwig, J.F.  “Intermolecular Migratory Insertion of Unactivated Olefins into Palladium–Nitrogen Bonds. Steric and Electronic Effects on the Rate of Migratory Insertion” J. Am. Chem. Soc. 2011, 133, 15661-15673. [doi]

Marquard, S.L.; Hartwig, J.F C(sp3)–O Bond-Forming Reductive Elimination of Ethers from Bisphosphine-Ligated Benzylpalladium(II) Aryloxide Complexes” Angew. Chem. Int. Ed. 2011, 50, 7119–7123.

Huang, Z.; Zhou, J. Hartwig, J.F. “N-H Activation of Hydrazines by Iridium(I). Double N-H Activation to Form Iridium Aminonitrene Complexes” J. Am. Chem. Soc. 2010 132, 11458-11460. [doi]

Hanley, P.S.; Markovic, D.; Hartwig, J.F. “Intermolecular Insertion of Ethylene and Octene into a Palladium-Amide Bond. Spectroscopic Evidence for an Ethylene Amido Intermediate“ J. Am. Chem. Soc. 2010, 132, 6302–6303. [doi]

Marquard, S. L.; Rosenfeld, D. C.; Hartwig, J. F. “C(sp3)-N Bond-Forming Reductive Elimination of Amines: Reactions of Bisphosphine-Ligated Benzylpalladium(II) Diarylamido Complexes” Angew. Chem. Int. Ed. 2010, 49, 793-796. [doi]

Tye, J. W.; Hartwig, J. F.  “Computational Studies on the Relative Rates for Migratory Insertions of Alkenes into Square-Planar Rhodium–Methyl, –Amide, and –Hydroxide Complexes” J. Am. Chem.  Soc. 2009, 131, 14703. [doi]

Zhao, P.; Hartwig, J. F. "Insertions of Ketones and Nitriles into Organorhodium(I) Complexes and b-Hydrocarbyl Eliminations from Rhodium(I) Alkoxo and Iminyl Complexes" Organometallics 2008, 27, 4749-4757. [doi]

Zhao, P., Incarvito, C.D., and J. F. Hartwig, Carbon-Oxygen Bond Formation between a Terminal Alkoxo Ligand and a Coordinated Olefin. Evidence for Olefin Insertion into a Rhodium-Alkoxide. J. Am. Chem. Soc., 2006, 128, 9642-9643. [doi]

Zhao, P., Incarvito, C. D., and J. F. Hartwig, Direct Observation of b-Aryl Eliminations from Rh(I) Alkoxides. J. Am. Chem. Soc., 2006, 128, 3124-3125. [doi]

Zhao, P., Krug, C., and J. F. Hartwig, Transfer of Amido Groups from Isolated Rhodium(I) Amides to Alkenes and Vinylarenes. J. Am. Chem. Soc., 2005, 127, 12066-12073. [doi]

Zhao, P. and J. F. Hartwig, b-Aryl Eliminations from Rh(I) Iminyl Complexes. J. Am. Chem. Soc., 2005, 127, 11618-11619. [doi]

Krug, C. and J. F. Hartwig, Imine Insertion into a Late Metal-Carbon Bond To Form a Stable Amido Complex. Journal of the American Chemical Society, 2004, 126, 2694-2695. [doi]

Stambuli, J. P., Incarvito, C. D., Buhl, M. and J. F. Hartwig, Synthesis, Structure, Theoretical Studies, and Ligand Exchange Reactions of Monomeric, T-Shaped Arylpalladium(II) Halide Complexes with an Additional, Weak Agostic Interaction.J. Am. Chem. Soc., 2004, 126, 1184-1194. [doi]

Yamashita, M. and J. F. Hartwig, Synthesis, Structure, and Reductive Elimination Chemistry of Three-Coordinate Arylpalladium Amido Complexes. J. Am. Chem. Soc., 2004. 126(17): p 5344-5345.
[doi]

Kanzelberger, M., Zhang, X., Emge, T. J., Goldman, A. S., Zhao, J., Incarvito, C. D., and J. F. Hartwig, Distinct Thermodynamics for the Formation and Cleavage of N-H Bonds in Aniline and Ammonia. Directly-Observed Reductive Elimination of Ammonia from an Isolated Amido Hydride Complex. J. Am. Chem. Soc., 2003. 125(45): p. 13644-13645.
[doi]

Mann, G., Shelby, Q., Roy, A. H., and J. F. Hartwig, Electronic and Steric Effects on the Reductive Elimination of Diaryl Ethers from Palladium(II). Organometallics, 2003. 22(13): p. 2775-2789.
[doi]

Roy, A. H. and J. F. Hartwig, Oxidative Addition of Aryl Tosylates to Palladium(0) and Coupling of Unactivated Aryl Tosylates at Room Temperature. J. Am. Chem. Soc., 2003. 125(29): p. 8704-8705.
[doi]

Yamashita, M., Cuevas Vicario, J. V., and J. F. Hartwig, Trans Influence on the Rate of Reductive Elimination. Reductive Elimination of Amines from Isomeric Arylpalladium Amides with Unsymmetrical Coordination Spheres. J. Am. Chem. Soc., 2003. 125(52): p. 16347-16360.
[doi]

Krug, C. and J. F. Hartwig, Direct observation of aldehyde insertion into rhodium-aryl and -alkoxide complexes. J. Am. Chem. Soc., 2002. 124(8): p. 1674-1679.
[doi]

Stambuli, J. P., Buhl, M., and J. F. Hartwig, Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. J. Am. Chem. Soc., 2002. 124(32): p. 9346-9347.
[doi]

Culkin, D. A. and J. F. Hartwig, C-C bond-forming reductive elimination of ketones, esters, and amides from isolated arylpalladium(II) enolates. J. Am. Chem. Soc., 2001. 123(24): p. 5816-5817.
[doi]

Roy, A. H. and J. F. Hartwig, Reductive elimination of aryl halides from palladium(II). J. Am. Chem. Soc., 2001. 123(6): p. 1232-1233.
[doi]

Zhao, J., Hesslink, H., and J. F. Hartwig, Mechanism of b-hydrogen elimination from square planar iridium(I) alkoxide complexes with labile dative ligands. J. Am. Chem. Soc., 2001. 123(30): p. 7220-7227.
[doi]

Ishiyama, T. and J. Hartwig, A Heck-type reaction involving carbon-heteroatom double bonds. Rhodium(I)-catalyzed coupling of aryl halides with N-pyrazyl aldimines. J. Am. Chem. Soc., 2000. 122(48): p. 12043-12044.
[doi]

Driver, M. S. and J. F. Hartwig, Oxidative addition and reductive elimination reactions of trans-[Ir(PPh3)2(CO)(NC4H4)] and trans,cis-[Ir(PPh3)2(H)2(CO)(NC4H4)] including N-H bond-forming reductive elimination of pyrrole. Organometallics, 1998. 17(6): p. 1134-1143.
[doi]

Hartwig, J. F., Carbon-heteroatom bond-forming reductive eliminations of amines, ethers, and sulfides. Accounts of Chemical Research, 1998. 31(12): p. 852-860.
[doi]

Mann, G., Baranano, D., Hartwig, J. F., Rheingold, A. L., and I. A. Guzei, Carbon-sulfur bond-forming reductive elimination involving sp-, sp2-, and sp3-hybridized carbon. Mechanism, steric effects, and electronic effects on sulfide formation. J. Am. Chem. Soc., 1998. 120(36): p. 9205-9219.
[doi]

Mann, G., Hartwig, J. F., Driver, M. S., and C. Fernandez-Rivas, Palladium-catalyzed C-N(sp2) bond formation: N-arylation of aromatic and unsaturated nitrogen and the reductive elimination chemistry of palladium azolyl and methyleneamido complexes. J. Am. Chem. Soc., 1998. 120(4): p. 827-828.
[doi]

Driver, M. S. and J. F. Hartwig, Carbon-nitrogen-bond-forming reductive elimination of arylamines from palladium(II) phosphine complexes. J. Am. Chem. Soc., 1997. 119(35): p. 8232-8245.
[doi]

Driver, M. S. and J. F. Hartwig, Energetics and mechanism of alkylamine N-H bond cleavage by palladium hydroxides: N-H activation by unusual acid-base chemistry. Organometallics, 1997. 16(26): p. 5706-5715.
[doi]

Driver, M. S. and J. F. Hartwig, General N-H activation of primary alkylamines by a late transition-metal complex. J. Am. Chem. Soc., 1996. 118(17): p. 4206-4207.
[doi]

Hartwig, J. F., Directly-observed b-hydrogen elimination of a late transition metal amido complex and unusual fate of imine byproducts. J. Am. Chem. Soc., 1996. 118(29): p. 7010-7011.
[doi]

Mann, G. and J. F. Hartwig, Palladium alkoxides: Potential intermediacy in catalytic amination, reductive elimination of ethers, and catalytic etheration. Comments on alcohol elimination from Ir(III). J. Am. Chem. Soc., 1996. 118(51): p. 13109-13110.
[doi]

Baranano, D. and J. F. Hartwig, Carbon-Heteroatom Bond-Forming Reductive Elimination - Mechanism, Importance of Trapping Reagents, and Unusual Electronic Effects During Formation of Aryl Sulfides. J. Am. Chem. Soc., 1995. 117(10): p. 2937-2938.
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Driver, M. S. and J. F. Hartwig, A Rare, Low-Valent Alkylamido Complex, a Diphenylamido Complex, and Their Reductive Elimination of Amines by 3-Coordinate Intermediates.J. Am. Chem. Soc., 1995. 117(16): p. 4708-4709.
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