7. Main-Group-Transition Metal Organometallics

Liskey, C. W., Wei C. S., Pahls, D. R., Hartwig J. F. “Pronounced Effects of Substituents on the Iridium-Catalyzed Borylation of Aryl C–H Bonds” Chem. Commun. 2009, 5603-5605. [doi]

Anastasi, N. R.; Waltz, K. M.; Weerakoon, W. L; Hartwig,J. F. "A short synthesis of tetraalkoxydiborane(4) reagents" Organometallics 2003, 22, 365-369.
[doi]

Hartwig, J. F.; Muhoro, C. N. "Mechanistic studies of titanocene-catalyzed alkene and alkyne hydroboration: Borane complexes as catalytic intermediates" Organometallics 2000, 19, 30-38.
[doi]

Schlecht, S.; Hartwig, J. F. "s-borane complexes of manganese and rhenium" Journal of the American Chemical Society 2000, 122, 9435-9443.
[doi]

Muhoro, C. N., He, X. M., and J. F. Hartwig, Titanocene borane sigma-complexes. Journal of the American Chemical Society, 1999, 121, 5033-5046.
[doi]

Muhoro, C. N. and J. F. Hartwig, Synthesis, structure, and reactivity of [Cp2Ti(HBcat)(PMe3)]: A monoborane sigma complex. Angewandte Chemie-International Edition, 1997, 36, 1510-1512.

Hartwig, J. F., Muhoro, C. N., He, X., Eisenstein, O., Bosque, R., and F. Maseras, Catecholborane bound to titanocene. Unusual coordination of ligand sigma-bonds. Journal of the American Chemical Society, 1996, 118, 10936-10937.
[doi]

Hartwig, J. F. and X. M. He, Reactivity of tungstenocene with B-B and B-H bonds versus C-H bonds. Angewandte Chemie-International Edition in English, 1996, 35, 315-317.

Hartwig, J. F. and X. M. He, Structural and reaction chemistry of tungstenocene boryl complexes. Organometallics, 1996, 15, 5350-5358.
[doi]

He, X. M. and J. F. Hartwig, Boryls bound to iron carbonyl. Structure of a rare bis(boryl) complex, synthesis of the first anionic boryl, and reaction chemistry that includes the synthetic equivalent of boryl anion transfer. Organometallics, 1996, 15, 400-407.
[doi]

He, X. M. and J. F. Hartwig, True metal-catalyzed hydroboration with titanium. Journal of the American Chemical Society, 1996, 118, 1696-1702.
[doi]

Rablen, P. R. and J. F. Hartwig, Accurate borane sequential bond dissociation energies by high-level ab initio computational methods. Journal of the American Chemical Society, 1996, 18, 4648-4653.
[doi]

Waltz, K.M., He, X., Muhoro, C., and J. F. Hartwig, Hydrocarbon Functionalization by Transition-Metal Boryls. Journal of the American Chemical Society, 1995, 117, 11357-11358.
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Hartwig, J. F. and S. R. De Gala, A Continuum Resulting from Equilibrium between 2 Structural Extremes in Tungstenocene and Niobocene Boryl and Hydridoborate Complexes - p-Bonding in a d2 Boryl System and the First d0 Boryl Complex. Journal of the American Chemical Society, 1994. 116(8): p. 3661-3662.
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Hartwig, J. F., Bhandari, S., and P. R. Rablen, Addition of Catecholborane to a Ruthenium-Alkyl - Evidence for Sigma-Bond Metathesis with a Low-Valent, Late Transition-Metal. Journal of the American Chemical Society, 1994. 116(5): p. 1839-1844.
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Hartwig, J. F. and S. Huber, Transition-Metal Boryl Complexes - Structure and Reactivity of CpFe(CO)2Bcat and CpFe(CO)2BPh2. Journal of the American Chemical Society, 1993. 115(11): p. 4908-4909.
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Rablen, P. R., Hartwig, J. F., and S. P. Nolan, First Transition Metal-Boryl Bond-Energy and Quantitation of Large Differences in Sequential Bond-Dissociation Energies of Boranes. Journal of the American Chemical Society, 1994. 116(9): p. 4121-4122.
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