1. C-C Bond Forming Cross-Couplings

   1b. Mechanism

Carrow, B. P.; Hartwig, J. F. “Distinguishing Between Pathways for Transmetalation in Suzuki-Miyaura Reactions” J. Am. Chem. Soc. 2011, ASAP. [doi]

Tan, Y.; Hartwig, J. F. “Assessment of the Intermediacy of Arylpalladium Carboxylate Complexes in the Direct Arylation of Benzene: Evidence for C-H Bond Cleavage by ‘Ligandless’ Species” J. Am. Chem. Soc. 2011, in press.

Carrow, B.P.; Hartwig, J.F. “Ligandless, Anionic, Arylpalladium Halide Intermediates in the Heck Reaction” J. Am. Chem. Soc. 2009, 132, 79-81. [doi]

Barrios-Landeros, F.; Carrow, B. P.; Hartwig, J. F. "Effect of Ligand Steric Properties and Halide Identity on the Mechanism for Oxidative Addition of Haloarenes to Trialkylphosphine Pd(0) Complexes." J. Am. Chem. Soc. 2009, 131, 8141-8154.
[doi]

Alexanian, E.J.; Hartwig, J.F. Mechanistic Study of β-Hydrogen Elimination from Organoplatinum(II) Enolate Complexes J. Am. Chem. Soc. 2008, 130, 15627-15635.
[doi]

Barrios-Landeros, F., Carrow, B.P., and J. F. Hartwig, Autocatalytic Oxidative Addition of PhBr to Pd(PtBu3)2 via Pd(PtBu3)2(H)(Br). J. Am. Chem. Soc. 2008 130(18) p. 5842-5843. [doi]

Culkin, D. A. and J. F. Hartwig, Carbon-Carbon Bond-Forming Reductive Elimination from Arylpalladium Complexes Containing Functionalized Alkyl Groups. Influence of Ligand Steric and Electronic Properties on Structure, Stability, and Reactivity. Organometallics, 2004. 23(14): p. 3398-3416.
[doi]

Roy, A. H. and J. F. Hartwig, Oxidative Addition of Aryl Sulfonates to Palladium(0) Complexes of Mono- and Bidentate Phosphines. Mild Addition of Aryl Tosylates and the Effects of Anions on Rate and Mechanism. Organometallics, 2004. 23(2): p. 194-202.
[doi]

Roy, A. H. and J. F. Hartwig, Reductive Elimination of Aryl Halides upon Addition of Hindered Alkylphosphines to Dimeric Arylpalladium(II) Halide Complexes. Organometallics, 2004. 23(7): p. 1533-1541.
[doi]

Stambuli, J. P., Incarvito, C. D., Buhl, M. and J. F. Hartwig, Synthesis, Structure, Theoretical Studies, and Ligand Exchange Reactions of Monomeric, T-Shaped Arylpalladium(II) Halide Complexes with an Additional, Weak Agostic Interaction. Journal of the American Chemical Society, 2004. 126(4): p 1184-1194.
[doi]

Yamashita, M. and J. F. Hartwig, Synthesis, Structure, and Reductive Elimination Chemistry of Three-Coordinate Arylpalladium Amido Complexes. Journal of the American Chemical Society, 2004. 126(17): p 5344-5345.
[doi]

Liu, X. and J. F. Hartwig, Palladium-catalyzed a-arylation of azlactones to form quaternary amino acid derivatives. Organic Letters, 2003. 5(11): p. 1915-1918.
[doi]