3. Amination of Olefins
Hanley, P.S.; Hartwig, J.F. “Intermolecular Migratory Insertion of Unactivated Olefins into Palladium–Nitrogen Bonds. Steric and Electronic Effects on the Rate of Migratory Insertion” J. Am. Chem. Soc. 2011, 133, 15661-15673. [doi]
Zhijian Liu, Z.; Yamamichi, H.; Madrahimov, S.T.; Hartwig, J.F. “Rhodium Phosphine-π-Arene Intermediates in the Hydroamination of Alkenes” J. Am. Chem. Soc. 2011, ASAP. [doi]
Julian, J.D.; Hartwig, J.F. “Intramolecular Hydroamination of Unbiased and Functionalized Primary Aminoalkenes Catalyzed by a Rhodium Aminophosphine Complex” J. Am. Chem. Soc. 2010 132, 13813-13822. [doi]
Hanley, P.S.; Markovic, D.; Hartwig, J.F. “Intermolecular Insertion of Ethylene and Octene into a Palladium-Amide Bond. Spectroscopic Evidence for an Ethylene Amido Intermediate“ J. Am. Chem. Soc. 2010, 132, 6302–6303. [doi]
Tye, J. W.; Hartwig, J. F. “Computational Studies on the Relative Rates for Migratory Insertions of Alkenes into Square-Planar Rhodium–Methyl, –Amide, and –Hydroxide Complexes” J. Am. Chem. Soc. 2009, 131, 14703-14712. [doi]
Zhou, J.; Hartwig, J. F. Intermolecular, Catalytic Asymmetric Hydroamination of Bicyclic Alkenes and Dienes in High Yield and Enantioselectivity. J. Am. Chem. Soc. 2008, 130, 12220-12221. [doi]
Liu, Z., and J. F. Hartwig, Mild, Rhodium-Catalyzed Intramolecular Hydroamination of Unactivated Terminal and Internal Olefins with Primary and Secondary Amines. J. Am. Chem. Soc. 2008 130(5) p. 1570-1571. [doi]
Johns, A.M., Liu, Z., and J. F. Hartwig, Primary tert- and sec-Allylamines via Palladium-Catalyzed Hydroamination and Allylic Substitution with Hydrazine and Hydroxylamine Derivatives. Angew. Chem., Int. Ed. 2007 46(38) p. 7259-7261 [doi]
Herzon, S. B., and J. F. Hartwig, Direct, Catalytic Hydroaminoalkylation of Unactivated Olefins with N-Alkyl Arylamines. J. Amer. Chem. Soc., 2007. 129(21): p. 6690-6691.
[doi]Johns, A. M, Tye, J. W., and J. F. Hartwig, Relative Rates for the Aminations of h3-Allyl and h3-Benzyl Complexes of Palladium. J. Am. Chem. Soc., 2006. 128(50): p. 16010-16011.
[doi]Rosenfeld, D. C., Shekhar, S., Takemiya, A., Utsunomiya, M., and J. F. Hartwig, Hydroamination and Hydroalkoxylation Catalyzed by Triflic Acid. Parallels to Reactions Initiated with Metal Triflates . Org. Lett., 2006. 8(19): p. 4179-4182.
[doi]Sakai, N., Ridder, A., J. F. Hartwig, Tropene Derivatives by Sequential Intermolecular and Transannular, Intramolecular Palladium-Catalyzed Hydroamination of Cycloheptatriene. J. Am. Chem. Soc., 2006. 128(25): p.8134-8135.
[doi]Johns, A.M., Sakai, N., Ridder, A., and J. F. Hartwig, Direct Measurement of the Thermodynamics of Vinylarene Hydroamination. J. Am. Chem. Soc., 2006. 128(29): p.9306-9307.
[doi]Johns, A. M., Utsunomiya, M., Incarvito, C. D., and J. F. Hartwig, A Highly Active Palladium Catalyst for Intermolecular Hydroamination. Factors that Control Reactivity and Additions of Functionalized Anilines to Dienes and Vinylarenes. J. Am. Chem. Soc., 2006. 128(6): p. 1828-1839.
[doi]Takaya, J. and J. F. Hartwig, Mechanistic Studies of Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes: Intermediates and Evidence for Catalysis through p-Arene Complexes. J. Am. Chem. Soc., 2005. 127(16): p. 5756-5757.
[doi]Utsunomiya, M. and J. F. Hartwig, Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes. Journal of the American Chemical Society, 2005. 126(9): p 2702-2703.
[doi]Kanzelberger, M., Zhang, X., Emge, T. J., Goldman, A. S., Zhao, J., Incarvito, C. D., and J. F. Hartwig, Distinct Thermodynamics for the Formation and Cleavage of N-H Bonds in Aniline and Ammonia. Directly-Observed Reductive Elimination of Ammonia from an Isolated Amido Hydride Complex. Journal of the American Chemical Society, 2003. 125(45): p. 13644-13645.
[doi]Utsunomiya, M. and J. F. Hartwig, Intermolecular, Markovnikov Hydroamination of Vinylarenes with Alkylamines. Journal of the American Chemical Society, 2003. 125(47): p. 14286-14287.
[doi]Utsunomiya, M., Kawatsura, M., and J. F. Hartwig, Palladium-Catalyzed Equilibrium Addition of Acidic OH Groups across Dienes. Angewandte Chemie International Edition, 2003. 42(47): p. 5865-5868.
[link]Utsunomiya, M., Kuwano, R., Kawatsura, M., and J. F. Hartwig, Rhodium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes. Journal of the American Chemical Society, 2003. 125(19): p. 5608-5609.
[doi]Nettekoven, U. and J. F. Hartwig, A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes. Journal of the American Chemical Society, 2002. 124(7): p. 1166-1167.
[doi]Pawlas, J., Nakao, Y., Kawatsura, M., J. F. Hartwig, A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: Catalyst selection, scope, and mechanism. Journal of the American Chemical Society, 2002. 124(14): p. 3669-3679.
[doi]Schlummer, B. and J. F. Hartwig, Bronsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines. Organic Letters, 2002. 4(9): p. 1471-1474.
[doi]Kawatsura, M. and J. F. Hartwig, Transition metal-catalyzed addition of amines to acrylic acid derivatives. A high-throughput method for evaluating hydroamination of primary and secondary alkylamines. Organometallics, 2001. 20(10): p. 1960-1964.
[doi]Lober, O., Kawatsura, M., and J. F. Hartwig, Palladium-catalyzed hydroamination of 1,3-dienes: A colorimetric assay and enantioselective additions. Journal of the American Chemical Society, 2001. 123(18): p. 4366-4367.
[doi]Kawatsura, M. and J. F. Hartwig, Palladium-catalyzed intermolecular hydroamination of vinylarenes using arylamines. Journal of the American Chemical Society, 2000. 122(39): p. 9546-9547.
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