
Since 1965, Professor Somorjai has proposed,
planned, and carried out a program to build the fundamental molecular basis
for the surface science of heterogeneous catalysis. He characterized the
structure of clean single crystal surfaces, and determined the structure
and bonding of adsorbed molecules. He used transition metal single crystal
surfaces as model catalysts and carried out catalytic reactions on these
crystal surfaces. He developed much of the instrumentation necessary for
studying molecular surface chemistry and catalysis at high reactant pressures
(atmospheres) on the small area crystals. These include high pressure reaction
cells that are combined with ultra high vacuum surface characterization
chambers, sum frequency generation (SFG)-surface vibrational spectroscopy,
and scanning tunneling microscopy (STM), which can be used to monitor surfaces
under reaction conditions, in situ. Since 1994, ordered arrays of nanoparticles
of transition metals fabricated by electron beam lithography, photolithography,
and colloid science techniques, have been studied and also utilized as
model catalysts. Since 1997, polymer surfaces, their molecular structure,
composition, chemistry, and tribology (friction, hardness), have been explored
by SFG and the atomic force microspe (AFM) for this purpose. Professor
Somorjai has educated a generation of leading scientists in the field.
Out of more than 115 Ph.D. students and 150 Posdoctoral Fellows, 60 hold
faculty positons.